{"id":"W1998769177","doi":"10.1021/jo0524728","title":"Competing Excited State Intramolecular Proton Transfer Pathways from Phenol to Anthracene Moieties","year":2006,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":51,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Anthracene; Chemistry; Intramolecular force; Photochemistry; Proton; Excited state; Solvent; Phenol; Methanol; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009123237,0.0002474293,0.00008660422,0.00004514454,0.00007737694,0.0001633584,0.0001777972,0.0002028105,0.001966402],"category_scores_gemma":[0.0001440059,0.00008645,0.00009732186,0.00004671203,0.0001748018,0.0002591044,0.0001115189,0.0002990519,0.0002712684],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000222364,"about_ca_system_score_gemma":0.000106768,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002956835,"about_ca_topic_score_gemma":0.0005670889,"domain_scores_codex":[0.999947,0.000008872458,0.000001907055,0.00001066886,0.00001277947,0.00001888873],"domain_scores_gemma":[0.9998939,0.00004466116,0.00002480837,0.000007610051,0.00001089426,0.00001818545],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008768784,0.00001022978,0.00009451028,0.00003550506,0.000002326094,0.00008029035,0.00002205499,0.0001779964,0.9980697,0.0002132064,0.00001506578,0.001191406],"study_design_scores_gemma":[0.000006975078,0.0002085787,0.000338538,0.000001182113,0.000002927715,0.00006066,0.00000893134,0.0003612308,0.9985363,0.00003153886,0.0004411262,0.000001830698],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957709,0.0003661271,0.002066933,0.00003912535,0.000005742009,0.00001149834,0.00006227411,0.00002279469,0.001654596],"genre_scores_gemma":[0.9976431,0.0002071508,0.0008834914,0.00001283847,0.000001636656,0.00000548815,0.00007806169,0.000004209838,0.001164055],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001966402,"threshold_uncertainty_score":0.006578326,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006767954851315766,"score_gpt":0.1945452702545069,"score_spread":0.1877773154031912,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}