{"id":"W1998869496","doi":"10.1021/jp036679l","title":"NMR Studies of Guest Dynamics in Clathrate Hydrates:  Spherical Tops SF6, SeF6 and CH4 in Structure II Hydrate","year":2003,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Methane Hydrates and Related Phenomena","field":"Environmental Science","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"","keywords":"Clathrate hydrate; Chemistry; Relaxation (psychology); Motional narrowing; Intermolecular force; Hydrate; Dipole; Spin–lattice relaxation; Molecular dynamics; Proton; Anisotropy; Chemical physics; Molecular physics; Spectral line; Computational chemistry; Molecule; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001211053,0.0002349823,0.0001925727,0.0001358819,0.0001983935,0.0001229912,0.0001581065,0.0001533083,0.0005826112],"category_scores_gemma":[0.0002797484,0.0001189634,0.0001563406,0.00009317099,0.0003091864,0.0001862252,0.0001547349,0.0002632439,0.0000652803],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002352336,"about_ca_system_score_gemma":0.000127928,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002665598,"about_ca_topic_score_gemma":0.001938526,"domain_scores_codex":[0.9999573,0.000005097581,0.000002029022,0.000009500284,0.00001021704,0.00001579661],"domain_scores_gemma":[0.9998134,0.00005000427,0.00005638498,0.00001042192,0.00003152401,0.00003835412],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001757943,0.00001249104,0.001403517,0.0000261486,0.000008828331,0.00005541179,0.00009694745,0.0003259345,0.9971356,0.00005425997,0.0000176466,0.0006874197],"study_design_scores_gemma":[0.00002000416,0.0004623415,0.03110352,0.000008957632,0.00002709352,0.0002179211,0.0001426019,0.006023124,0.9614267,0.00004217437,0.0005034871,0.00002194977],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9995207,0.00007254591,0.0002327579,0.000006525759,0.00000157703,0.000001973095,0.00004183156,0.000008189132,0.0001139483],"genre_scores_gemma":[0.9990799,0.0001058581,0.0004627328,0.000005891976,0.0000024978,0.000004164285,0.0001162792,0.000007328992,0.0002151923],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002665598,"threshold_uncertainty_score":0.005300105,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008168399052658154,"score_gpt":0.2211157977325346,"score_spread":0.2129473986798764,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}