{"id":"W1998937636","doi":"10.1139/v08-125","title":"Zinc and iron complexes of a helix-directing (1<i>R</i>,2<i>R</i>)-cyclohexyl salen ligand with phenanthryl sidearms","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Molecular spectroscopy and chirality","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Zinc; Diastereomer; Crystallography; Ligand (biochemistry); Molecule; Metal; Condensation; Stereochemistry; Copper; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005504569,0.0001053797,0.0001166779,0.00008022115,0.00009964019,0.0001178678,0.0002491582,0.0001045656,0.001215893],"category_scores_gemma":[0.00009189359,0.00006398455,0.00004700435,0.00006370071,0.0001236249,0.00006247914,0.0001226636,0.000120072,0.0001191449],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003485448,"about_ca_system_score_gemma":0.00008503042,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001392761,"about_ca_topic_score_gemma":0.00234588,"domain_scores_codex":[0.9999661,0.000005245231,0.000001615324,0.000006777315,0.00001252402,0.000007702773],"domain_scores_gemma":[0.999983,0.000004380915,0.000003557748,0.000001586838,0.000001855837,0.000005634451],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008418685,0.00007043113,0.0006808848,0.0001018187,0.00001037139,0.0001838946,0.00005175013,0.00206805,0.9902081,0.001565053,0.0004114342,0.003806411],"study_design_scores_gemma":[0.00009301443,0.0004317795,0.001626602,0.000007832955,0.000009551656,0.0001440302,0.00002593915,0.01315576,0.9819666,0.0001374676,0.002393993,0.000007346593],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966522,0.0001375653,0.0006007443,0.00002469188,0.000007109188,0.000007955324,0.00003938526,0.00002090832,0.002509401],"genre_scores_gemma":[0.9975824,0.00007683301,0.0007906018,0.000009950808,0.000001678619,0.000004198669,0.00006418034,0.000004118244,0.001465929],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001392761,"threshold_uncertainty_score":0.0040676,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008553126883803101,"score_gpt":0.2049473413164254,"score_spread":0.1963942144326223,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}