{"id":"W1999112480","doi":"10.1002/pola.22937","title":"Syntheses and characterization of physically crosslinked hydrogels from dithiocarbamate‐derived polyurethane macroiniferter","year":2008,"lang":"en","type":"article","venue":"Journal of Polymer Science Part A Polymer Chemistry","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Self-healing hydrogels; Polyurethane; Polymer chemistry; Copolymer; Chemistry; Swelling; Dithiocarbamate; Diffusion; Reaction rate constant; Nuclear chemistry; Chemical engineering; Kinetics; Materials science; Polymer; Organic chemistry; Composite material","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001934906,0.0003894656,0.0007220288,0.0001084922,0.0002919178,0.00006941531,0.0006767443,0.0001932479,0.0007521402],"category_scores_gemma":[0.0001276444,0.0003451749,0.0002125657,0.0003783512,0.001530794,0.0009635052,0.0001560996,0.0003222013,0.000004645522],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005236031,"about_ca_system_score_gemma":0.000410227,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002423109,"about_ca_topic_score_gemma":3.082693e-7,"domain_scores_codex":[0.9969252,0.00002855964,0.001105004,0.0004879307,0.0009431764,0.0005101406],"domain_scores_gemma":[0.9971716,0.0001743635,0.001508557,0.0004992906,0.000256632,0.0003895744],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001553427,0.0001853912,0.003315335,0.00006072871,0.00007588506,0.00003190007,0.0008612429,1.963357e-7,0.991487,0.00000792934,0.000004624484,0.003814408],"study_design_scores_gemma":[0.0005147731,0.00002986153,0.00204433,0.0003463502,0.00008301881,0.0003448429,0.0001578448,0.00008812527,0.9959487,0.00001328581,0.00008071449,0.0003482081],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.99618,0.002265626,0.0002258529,0.000242721,0.0002230558,0.00003764094,0.0001472086,0.00003192961,0.0006459574],"genre_scores_gemma":[0.9980617,0.0003459391,0.00005883756,0.0001056362,0.0006837,0.000005890995,0.00002764377,0.00004367295,0.0006669554],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004461629,"threshold_uncertainty_score":0.9999,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01396013231963511,"score_gpt":0.228057356707898,"score_spread":0.2140972243882629,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}