{"id":"W1999136266","doi":"10.1139/v99-245","title":"Pseudo-oxocarbons complexes - complexation of 2,4-bis(dicyanomethylene)-cyclobutane-1,3-dione dianion with copper. X-ray identification and electrochemical properties of the dianion and copper(I) and (II) complexes","year":2000,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Inorganic and Organometallic Chemistry","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Triclinic crystal system; Chemistry; Copper; Monoclinic crystal system; Crystallography; Electrochemistry; Crystal structure; Ligand (biochemistry); Nitrile; Cyclobutane; Stereochemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001848303,0.000270434,0.000492236,0.00005181849,0.0002636092,0.00005614177,0.0002971095,0.0001925784,0.000484641],"category_scores_gemma":[0.0001163434,0.0002100023,0.00007467353,0.0002012672,0.001011029,0.0001472537,0.00003993,0.0003466512,2.447324e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001254601,"about_ca_system_score_gemma":0.000597433,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004407821,"about_ca_topic_score_gemma":0.0003153821,"domain_scores_codex":[0.9984015,0.00002599847,0.0006880144,0.0002752416,0.0003040498,0.0003052324],"domain_scores_gemma":[0.998495,0.00006434017,0.000542145,0.0003049072,0.0002167115,0.0003768483],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008191385,0.00003969107,0.006868516,0.0006243203,0.00009867232,0.000003948968,0.000611292,0.000004311905,0.9911588,0.0000257154,0.0001566363,0.0003261557],"study_design_scores_gemma":[0.0008121805,0.00004480653,0.006542806,0.0004709136,0.0001242045,0.0006418428,0.00072517,0.00004191093,0.9894667,0.00007882938,0.0008106063,0.0002400847],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9950318,0.002991941,0.000009806973,0.0005221982,0.0000184098,0.00008184661,0.00008076794,0.000008366728,0.001254811],"genre_scores_gemma":[0.9987463,0.000390324,0.0001221024,0.00003211875,0.000105441,0.00000309094,0.00002974898,0.0000311919,0.0005396866],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003714444,"threshold_uncertainty_score":0.8563644,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007988538874968719,"score_gpt":0.1804108028028666,"score_spread":0.1724222639278978,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}