{"id":"W1999181234","doi":"10.1107/s0108270100006508","title":"(<i>R</i>)-(+)-2,2′-Bis(diphenylphosphinoyl)-1,1′-binaphthyl","year":2000,"lang":"en","type":"article","venue":"Acta Crystallographica Section C Crystal Structure Communications","topic":"Crystal structures of chemical compounds","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"BINAP; Toluene; Chemistry; Oxide; Peroxide; Medicinal chemistry; Polymer chemistry; Catalysis; Enantioselective synthesis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001687898,0.0008540451,0.0006797928,0.0003001212,0.001471655,0.000410214,0.003266314,0.0007816482,0.02995696],"category_scores_gemma":[0.0001253482,0.0008764321,0.0006102037,0.001525701,0.001176256,0.0006827533,0.0006623266,0.001927057,0.000002623264],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000317758,"about_ca_system_score_gemma":0.0001399085,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002713837,"about_ca_topic_score_gemma":0.0006141411,"domain_scores_codex":[0.9958836,0.0001166412,0.00107891,0.001061928,0.0008505994,0.00100833],"domain_scores_gemma":[0.9939116,0.000410647,0.0003620195,0.004482588,0.0002866793,0.0005465114],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0001750384,0.000192368,0.001044195,0.00007567216,0.0002110499,0.00000560757,0.0002237998,0.00005277316,0.9904186,0.0003491613,0.003372955,0.003878745],"study_design_scores_gemma":[0.001096925,0.00006351066,0.001884467,0.00005941294,0.0001254869,0.000316667,0.0002003559,0.0002223813,0.002410456,0.008123749,0.9844608,0.001035798],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8981369,0.001146927,0.0001116257,0.002359666,0.0002913075,0.0003462,0.0004821707,0.001351262,0.09577399],"genre_scores_gemma":[0.9931149,0.0006855337,0.002481836,0.0003992824,0.0004966235,0.00009391057,0.001024985,0.0001610777,0.001541884],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.9880082,"threshold_uncertainty_score":0.9998283,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01033537689285506,"score_gpt":0.2376182885511404,"score_spread":0.2272829116582853,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}