{"id":"W1999460393","doi":"10.1139/v10-053","title":"Organocatalysis in the stereoselective bromohydrin reaction of alkenes","year":2010,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Vanadium and Halogenation Chemistry","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Stereoselectivity; Organocatalysis; Organic chemistry; Stereochemistry; Catalysis; Enantioselective synthesis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002164479,0.0003110194,0.0001624463,0.0001601055,0.0001222274,0.0001754735,0.0002609031,0.0001867502,0.000696754],"category_scores_gemma":[0.0001326401,0.0001262113,0.0001249788,0.0001278966,0.0002424091,0.0002233073,0.0002026972,0.0002132176,0.0003331422],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000247753,"about_ca_system_score_gemma":0.000232472,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001255003,"about_ca_topic_score_gemma":0.002090924,"domain_scores_codex":[0.9999015,0.00002014311,0.000005978087,0.00001758855,0.0000206849,0.00003399625],"domain_scores_gemma":[0.9999596,0.000007810254,0.000009918573,0.000007574507,0.0000075814,0.000007522331],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001154806,0.00001261139,0.0001589813,0.00005304775,0.000005550522,0.00007121328,0.00003481887,0.0001521077,0.9966671,0.0003376589,0.00004749436,0.002343844],"study_design_scores_gemma":[0.000007000091,0.00005518235,0.0003581981,0.000001893921,0.000005711068,0.00007545397,0.000007751624,0.0001478574,0.9979122,0.00001824825,0.001407811,0.000002585054],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9877318,0.001447839,0.004685601,0.00007619979,0.00002667482,0.00001813949,0.0001360702,0.0001294848,0.005748169],"genre_scores_gemma":[0.9956808,0.0008150464,0.001454461,0.00001410809,0.000005988687,0.000004142253,0.000113262,0.00001847175,0.001893776],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001255003,"threshold_uncertainty_score":0.002495348,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006960900470321373,"score_gpt":0.2060834256037296,"score_spread":0.1991225251334082,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}