{"id":"W1999464756","doi":"10.1021/om020445r","title":"A Study of Unsaturated Pyrazolate-Bridged Diruthenium Carbonyl Complexes","year":2002,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"","keywords":"Chemistry; Steric effects; Ligand (biochemistry); Pyridine; Stereochemistry; Toluene; Isocyanide; Ruthenium; Crystallography; Medicinal chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002125509,0.0004415929,0.0003865466,0.0001770488,0.000310122,0.0003243984,0.0004297796,0.0003254734,0.001657422],"category_scores_gemma":[0.0004251889,0.0002122267,0.0001269131,0.0001951468,0.0002382628,0.0002758248,0.0002443691,0.000349903,0.0003599116],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006513734,"about_ca_system_score_gemma":0.000259879,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001274934,"about_ca_topic_score_gemma":0.002014125,"domain_scores_codex":[0.9997613,0.00004675965,0.00001063264,0.00004866349,0.00006330552,0.00006945984],"domain_scores_gemma":[0.9998952,0.00001859659,0.00002484453,0.0000117076,0.00002365664,0.00002613237],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002498414,0.00004027734,0.0002324398,0.0001869322,0.00001827663,0.0001976851,0.0001788506,0.000475632,0.9953589,0.0006430139,0.0001128298,0.002305296],"study_design_scores_gemma":[0.00004806854,0.0005191551,0.0009487951,0.000008759403,0.00002039689,0.0003651971,0.00005091057,0.0007658944,0.9923949,0.00007199006,0.004791019,0.000015054],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942469,0.001053756,0.0009720003,0.00003851668,0.00001022813,0.00002915182,0.00009173452,0.00003833258,0.003519464],"genre_scores_gemma":[0.9961911,0.0005361978,0.0008570619,0.00001483086,0.000004587073,0.0000149993,0.0003027932,0.00001667611,0.002061559],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001657422,"threshold_uncertainty_score":0.005544662,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03431699046870003,"score_gpt":0.2228652718700527,"score_spread":0.1885482814013527,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}