{"id":"W1999482485","doi":"10.1055/s-2001-16797","title":"One Pot Conversion of Ketoses into Sugar β-Peptides via a Ritter Reaction","year":2001,"lang":"en","type":"article","venue":"Synlett","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Ritter reaction; Organic chemistry; Glycopeptide; Intramolecular force; Lewis acids and bases; Amino acid; Nitrile; Sugar; Combinatorial chemistry; Catalysis; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003382752,0.0006517436,0.0003578448,0.0003263589,0.0001909606,0.0001721848,0.0003556772,0.0003928716,0.001627802],"category_scores_gemma":[0.0001877498,0.0002339756,0.0002959721,0.0002321017,0.0002092648,0.0004628866,0.0004132804,0.0007819836,0.001048624],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001423135,"about_ca_system_score_gemma":0.0002197823,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001089873,"about_ca_topic_score_gemma":0.0002275427,"domain_scores_codex":[0.9998073,0.00003621973,0.00001867981,0.00003797399,0.00003518209,0.00006465676],"domain_scores_gemma":[0.9999257,0.00001535623,0.00002043272,0.00001683362,0.00000697951,0.00001471254],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001630632,0.000122413,0.0001482059,0.0001599027,0.00003091259,0.0005072213,0.0001636889,0.0004409328,0.9851229,0.001687494,0.0003427664,0.01111049],"study_design_scores_gemma":[0.00003721118,0.0006087705,0.0006081107,0.000007146706,0.00002080868,0.000776784,0.00002267156,0.0005245335,0.9914979,0.0002338583,0.005635547,0.00002648843],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9021398,0.002310408,0.07331777,0.0003041645,0.000200832,0.0003549809,0.0005861811,0.0007641635,0.02002178],"genre_scores_gemma":[0.9582125,0.00272361,0.02734958,0.0001446356,0.00003380541,0.0002063237,0.0004195626,0.00008979656,0.01082022],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001627802,"threshold_uncertainty_score":0.00544554,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01317220325521532,"score_gpt":0.216837641159536,"score_spread":0.2036654379043207,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}