{"id":"W1999575823","doi":"10.1139/v10-106","title":"Reactions of toluquinone – cyclopentadiene Diels –Alder epoxide adducts with nucleophiles under heterogeneous conditions","year":2010,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Bioactive Compounds and Antitumor Agents","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Epoxide; Cyclopentadiene; Chemistry; Nucleophile; Adduct; Sulfur; Organic chemistry; Diels–Alder reaction; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001460172,0.000148781,0.0002382376,0.0000790302,0.0002136917,0.00002139612,0.0002522051,0.0001867174,0.004881849],"category_scores_gemma":[0.00003960088,0.0001337159,0.000102689,0.0001103182,0.0005666985,0.0001114039,0.00001290758,0.0007589063,0.00001022871],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000621541,"about_ca_system_score_gemma":0.0006834633,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002887998,"about_ca_topic_score_gemma":0.002833875,"domain_scores_codex":[0.9990916,0.00003653342,0.0003434979,0.0001306102,0.0001026248,0.0002951493],"domain_scores_gemma":[0.9984362,0.00007378061,0.000335384,0.0001541849,0.0002870575,0.000713368],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006628595,0.0001301836,0.009276808,0.00005008827,0.0003461133,0.0004571327,0.0001288585,0.0002781108,0.9856385,0.0001668833,0.003222291,0.0002387659],"study_design_scores_gemma":[0.001192239,0.00009874689,0.01033837,0.0000689888,0.0001857032,0.003475106,0.0002990082,0.00001474836,0.9039367,0.0004600146,0.07967788,0.0002524254],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9920521,0.000183445,0.00001530164,0.0009236783,0.0006321063,0.00006420752,0.0001731986,0.000005889466,0.005950038],"genre_scores_gemma":[0.9984203,0.00003843025,0.000137619,0.0003421677,0.0002830401,0.000002620761,0.00001634334,0.00001850123,0.0007409908],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08170171,"threshold_uncertainty_score":0.9960278,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05207285412963607,"score_gpt":0.3524610069553192,"score_spread":0.3003881528256831,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}