{"id":"W1999575823","doi":"10.1139/v10-106","title":"Reactions of toluquinone – cyclopentadiene Diels –Alder epoxide adducts with nucleophiles under heterogeneous conditions","year":2010,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Bioactive Compounds and Antitumor Agents","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Epoxide; Cyclopentadiene; Chemistry; Nucleophile; Adduct; Sulfur; Organic chemistry; Diels–Alder reaction; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002645921,0.0004322738,0.0002050673,0.0001890053,0.0001718563,0.0001791559,0.000186535,0.0002200589,0.001623488],"category_scores_gemma":[0.0002257831,0.0002292233,0.000177507,0.0002097143,0.0002216359,0.0003722035,0.0002158558,0.0004562628,0.0004648985],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000228339,"about_ca_system_score_gemma":0.0002086922,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005186875,"about_ca_topic_score_gemma":0.001755272,"domain_scores_codex":[0.9998351,0.00002358309,0.000008101323,0.00004046407,0.00004474345,0.00004802245],"domain_scores_gemma":[0.9998901,0.00002770917,0.00003137678,0.00001361675,0.00001785744,0.00001937314],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001037684,0.00002134414,0.0001103221,0.00005240651,0.00001218921,0.000109334,0.00008363801,0.000321306,0.9972942,0.0003487607,0.00006788396,0.00147477],"study_design_scores_gemma":[0.00001093951,0.0001415865,0.0004559971,0.000001926774,0.000006665325,0.00005947644,0.00001114687,0.000269027,0.9978839,0.00004848209,0.001106235,0.00000464076],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.985671,0.0007994101,0.01042968,0.00005602852,0.00003408928,0.0000718928,0.0002077908,0.000071641,0.002658408],"genre_scores_gemma":[0.9939932,0.0007097721,0.002520583,0.0000177434,0.000008449761,0.00002562034,0.0001865987,0.00001757004,0.002520499],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001623488,"threshold_uncertainty_score":0.005431116,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05207285412963607,"score_gpt":0.3524610069553192,"score_spread":0.3003881528256831,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}