{"id":"W1999712523","doi":"10.1002/cssc.201100413","title":"Highly Stable Noble‐Metal Nanoparticles in Tetraalkylphosphonium Ionic Liquids for in situ Catalysis","year":2011,"lang":"en","type":"article","venue":"ChemSusChem","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":38,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"University of Saskatchewan","keywords":"Ionic liquid; Nanoparticle; Halide; Hexafluorophosphate; Phosphonium; Catalysis; Inorganic chemistry; Chemistry; Metal; Sodium borohydride; Borohydride; Noble metal; Palladium; Ionic bonding; Bromide; Photochemistry; Organic chemistry; Materials science; Nanotechnology; Ion","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002213317,0.000496218,0.000299296,0.0002697732,0.0001676516,0.0004159223,0.0004502787,0.0004307897,0.0008212489],"category_scores_gemma":[0.0002015815,0.0004068317,0.0002734759,0.0001886997,0.0003169716,0.0003564787,0.0003944007,0.0004836157,0.0006031512],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004778703,"about_ca_system_score_gemma":0.0002432099,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006470291,"about_ca_topic_score_gemma":0.001474261,"domain_scores_codex":[0.9997721,0.00003052775,0.00002411027,0.00004899712,0.00007854876,0.00004577988],"domain_scores_gemma":[0.9999006,0.00002135002,0.00002976826,0.00001145689,0.00002360849,0.00001317282],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001299346,0.000004320209,0.00002213778,0.0000244969,0.000002519127,0.00002166595,0.00001308744,0.00007139656,0.9989445,0.00008918309,0.0000178704,0.0007759513],"study_design_scores_gemma":[0.000002144122,0.00001742877,0.00003626652,8.655041e-7,0.000003372952,0.00001654494,0.000003266615,0.0003229122,0.9992199,0.00001201492,0.000364139,0.000001188368],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9678316,0.001399758,0.02615761,0.0002010876,0.00006239,0.00006629698,0.0001393786,0.0003887653,0.003753182],"genre_scores_gemma":[0.9822974,0.0007332463,0.01250838,0.00006346374,0.00001307719,0.00005368406,0.000205804,0.00008188558,0.00404305],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008212489,"threshold_uncertainty_score":0.003467143,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02465021107913836,"score_gpt":0.2225989335139558,"score_spread":0.1979487224348174,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}