{"id":"W1999712523","doi":"10.1002/cssc.201100413","title":"Highly Stable Noble‐Metal Nanoparticles in Tetraalkylphosphonium Ionic Liquids for in situ Catalysis","year":2011,"lang":"en","type":"article","venue":"ChemSusChem","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":38,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"University of Saskatchewan","keywords":"Ionic liquid; Nanoparticle; Halide; Hexafluorophosphate; Phosphonium; Catalysis; Inorganic chemistry; Chemistry; Metal; Sodium borohydride; Borohydride; Noble metal; Palladium; Ionic bonding; Bromide; Photochemistry; Organic chemistry; Materials science; Nanotechnology; Ion","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002147311,0.0001993738,0.0002900822,0.00009061935,0.00005187142,0.000017941,0.0002898393,0.0001442935,0.0001179476],"category_scores_gemma":[0.00007750928,0.0001890833,0.0001092032,0.0004717461,0.00005087712,0.0001860556,0.00008844276,0.0002035553,0.00006391101],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001883222,"about_ca_system_score_gemma":0.0000627158,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004229254,"about_ca_topic_score_gemma":0.000155399,"domain_scores_codex":[0.9985045,0.000006667628,0.0004481007,0.0003722633,0.0001240469,0.000544444],"domain_scores_gemma":[0.9993568,0.00005790338,0.00005383473,0.0003793854,0.00005324633,0.00009881621],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007807356,0.000271614,0.0002206423,0.0000735853,0.00002207553,0.000002985497,0.0007372163,0.00009849583,0.9943303,0.003349149,0.000194341,0.0006214583],"study_design_scores_gemma":[0.0008612862,0.00004206597,0.0002457786,0.00003707934,0.00001988966,0.000001758953,0.0002636684,0.002462524,0.9929207,0.0002433337,0.002639001,0.0002628888],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9948574,0.0005747836,0.0003385887,0.0001739222,0.00007523176,0.0003108693,0.000007562775,0.0001054124,0.003556217],"genre_scores_gemma":[0.9959815,0.00003213268,0.002172236,0.00004953301,0.00006147395,0.0005113386,0.00003081605,0.00004305005,0.001117938],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003105815,"threshold_uncertainty_score":0.7710595,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02465021107913836,"score_gpt":0.2225989335139558,"score_spread":0.1979487224348174,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}