{"id":"W1999798871","doi":"10.1021/ic100383p","title":"Syntheses and Multi-NMR Study of<i>fac</i>- and<i>mer</i>-OsO<sub>3</sub>F<sub>2</sub>(NCCH<sub>3</sub>) and the X-ray Crystal Structure (<i>n</i>= 2) and Raman Spectrum (<i>n</i>= 0) of<i>fac</i>-OsO<sub>3</sub>F<sub>2</sub>(NCCH<sub>3</sub>)·<i>n</i>CH<sub>3</sub>CN","year":2010,"lang":"yi","type":"article","venue":"Inorganic Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Crystallography; Solvent; Raman spectroscopy; Molecule; Crystal structure; NMR spectra database; Adduct; Nuclear magnetic resonance spectroscopy; Dissolution; Stereochemistry; Spectral line; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004838494,0.0001958091,0.00009571573,0.00008905953,0.0001589837,0.00008584579,0.0001501309,0.0001291221,0.001173168],"category_scores_gemma":[0.0001201108,0.00008577027,0.00008423603,0.0001178647,0.0001385334,0.0001831394,0.00008761029,0.0002268287,0.0002216042],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002493514,"about_ca_system_score_gemma":0.000233894,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001091675,"about_ca_topic_score_gemma":0.002250039,"domain_scores_codex":[0.9999648,0.000002029972,0.000002078735,0.000008833476,0.00001467866,0.000007617191],"domain_scores_gemma":[0.999921,0.000006495954,0.00002967968,0.000008867305,0.00001833106,0.00001560404],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004634625,0.0000125952,0.0001551186,0.00003963785,0.000002054263,0.00003919392,0.00002992693,0.0001911443,0.9968208,0.0001546168,0.00007630741,0.002432274],"study_design_scores_gemma":[0.000003086611,0.00009001511,0.001119388,0.000002610783,0.000004531787,0.00007663095,0.00001826869,0.0003134061,0.9959434,0.00003946546,0.002382827,0.000006383358],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.985544,0.0008770412,0.006715354,0.0000692761,0.00002279121,0.00005686618,0.0005693624,0.0001467871,0.005998438],"genre_scores_gemma":[0.9862075,0.000539349,0.008205015,0.00004275728,0.000006185755,0.00004351149,0.0006407429,0.00005478255,0.004260259],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001173168,"threshold_uncertainty_score":0.003924668,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005827537074907029,"score_gpt":0.1959236073770459,"score_spread":0.1900960703021389,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}