{"id":"W1999817455","doi":"10.1021/ja030094n","title":"Ketonization of Incarcerated Acetophenone Enol","year":2003,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Enol; Acetophenone; Protonation; Keto–enol tautomerism; Photochemistry; Carbon fibers; Molecule; Proton; Base (topology); Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001470581,0.0001055022,0.0002908662,0.00000859042,0.00004478133,0.000009797588,0.0002568239,0.00006654407,0.0002254917],"category_scores_gemma":[0.0003435981,0.000071058,0.0004163566,0.0003551979,0.0002119254,0.00004840368,0.00004779834,0.0003677504,0.000001156892],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001665209,"about_ca_system_score_gemma":0.0001089488,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001174747,"about_ca_topic_score_gemma":9.909778e-8,"domain_scores_codex":[0.9990363,0.00001831545,0.0003841261,0.00009493171,0.0003092832,0.0001570063],"domain_scores_gemma":[0.9986061,0.0001016795,0.0007864867,0.0002047967,0.0002128177,0.00008805805],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002238017,0.0001067589,0.00026836,0.0000175209,0.00007797324,4.192908e-7,0.0001281393,0.00001169059,0.9969067,0.0001226508,0.00111934,0.001218087],"study_design_scores_gemma":[0.0003872926,0.00001636559,0.00002842336,0.0000345749,0.00005606563,0.00004976525,0.0005212266,0.00006653946,0.9934961,0.0005711103,0.0046945,0.00007808115],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9967658,0.00006301975,0.0004997816,0.0002104203,0.00005576318,0.00002041394,0.000004502426,0.000009066319,0.002371244],"genre_scores_gemma":[0.9959335,0.00009368463,0.003424546,0.0001789303,0.00009904846,0.000001029318,0.000001227283,0.00001536875,0.000252682],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00357516,"threshold_uncertainty_score":0.2897661,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008540719973099353,"score_gpt":0.236023174039977,"score_spread":0.2274824540668776,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}