{"id":"W1999865652","doi":"10.1002/chin.200546236","title":"Asymmetric Induction in Organic Photochemistry via the Solid‐State Ionic Chiral Auxiliary Approach","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Asymmetric induction; Solid-state; Ionic bonding; Chiral auxiliary; Combinatorial chemistry; Photochemistry; Organic chemistry; Enantioselective synthesis; Physical chemistry; Ion; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001143301,0.0001851845,0.0001857717,0.00003842833,0.0001295268,0.00003227655,0.0002215835,0.00005553895,0.0004482315],"category_scores_gemma":[0.00001067732,0.0001343971,0.00008872808,0.0004848697,0.00008067109,0.0001533147,0.00009860781,0.0003874462,0.00005412552],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001237938,"about_ca_system_score_gemma":0.00003919707,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004355344,"about_ca_topic_score_gemma":0.000002204903,"domain_scores_codex":[0.9990139,7.380189e-7,0.0002728013,0.0002059388,0.0001485853,0.00035806],"domain_scores_gemma":[0.9995698,0.00003340149,0.0000927857,0.0002237909,0.00002458671,0.00005561348],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001543811,0.001314589,0.007651513,0.0001703775,0.0004288461,0.000001934159,0.004462897,0.00007428429,0.1857775,0.002234166,0.01845635,0.7792731],"study_design_scores_gemma":[0.0004863428,0.00001276346,0.0009301737,0.00001145867,0.0000153053,0.000003647225,0.000442635,0.0005816914,0.9908366,0.001462796,0.00499161,0.0002250414],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.4679601,0.0002418398,0.00009260036,0.0001914486,0.00007258249,0.0002584207,0.000007667656,0.0000481779,0.5311272],"genre_scores_gemma":[0.995785,0.00001610052,0.00007648556,0.00007391833,0.0004798317,0.00008603989,0.0000498722,0.00001380666,0.003418947],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.805059,"threshold_uncertainty_score":0.5480554,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008115165390335752,"score_gpt":0.2381257324623557,"score_spread":0.2300105670720199,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}