{"id":"W1999887754","doi":"10.1021/ic502384w","title":"Lanthanide Directed Self-Assembly of Highly Luminescent Supramolecular “Peptide” Bundles from α-Amino Acid Functionalized 2,6-Bis(1,2,3-triazol-4-yl)pyridine (btp) Ligands","year":2015,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":51,"is_retracted":false,"has_abstract":true,"ca_institutions":"Trinity College","funders":"Irish Research Council; Science Foundation Ireland; Trinity College Dublin; Irish Research Council for Science, Engineering and Technology","keywords":"Chemistry; Lanthanide; Supramolecular chemistry; Pyridine; Luminescence; Ligand (biochemistry); Titration; Fluorescence; Chelation; Photochemistry; Stereochemistry; Combinatorial chemistry; Crystallography; Ion; Crystal structure; Physical chemistry; Medicinal chemistry; Inorganic chemistry; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009524383,0.0002555762,0.0001760925,0.0001177087,0.00009839611,0.0002688981,0.0001879805,0.0002018061,0.0005073166],"category_scores_gemma":[0.0001476464,0.0001413923,0.0001238017,0.0001070848,0.0001126443,0.0001657699,0.0001380146,0.0002461777,0.0002998472],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002810999,"about_ca_system_score_gemma":0.0001126393,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002903524,"about_ca_topic_score_gemma":0.0006479723,"domain_scores_codex":[0.9999267,0.00001172578,0.000004797423,0.00002234476,0.00001138527,0.0000229761],"domain_scores_gemma":[0.9999193,0.00001074568,0.00002609938,0.000006148012,0.000009610731,0.00002800962],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000297979,0.00001300373,0.00006092225,0.00002036347,0.000002840689,0.00002832686,0.0000151847,0.0001969015,0.9985482,0.00004474624,0.00002796412,0.001011826],"study_design_scores_gemma":[0.00001220893,0.0001721211,0.001156157,0.000003626054,0.000006721687,0.00008453488,0.00001180384,0.002111796,0.9952565,0.00002375414,0.001155088,0.000005651339],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9951786,0.0003405339,0.003236499,0.00003325181,0.00001378296,0.00002353144,0.00008167905,0.0001425616,0.0009495887],"genre_scores_gemma":[0.9936526,0.0002033178,0.004318522,0.00004364166,0.000006050253,0.00003116693,0.0002170924,0.00003080664,0.001496812],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005073166,"threshold_uncertainty_score":0.002039492,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01614838522480597,"score_gpt":0.2227845421785942,"score_spread":0.2066361569537882,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}