{"id":"W1999887754","doi":"10.1021/ic502384w","title":"Lanthanide Directed Self-Assembly of Highly Luminescent Supramolecular “Peptide” Bundles from α-Amino Acid Functionalized 2,6-Bis(1,2,3-triazol-4-yl)pyridine (btp) Ligands","year":2015,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":51,"is_retracted":false,"has_abstract":true,"ca_institutions":"Trinity College","funders":"Irish Research Council; Science Foundation Ireland; Trinity College Dublin; Irish Research Council for Science, Engineering and Technology","keywords":"Chemistry; Lanthanide; Supramolecular chemistry; Pyridine; Luminescence; Ligand (biochemistry); Titration; Fluorescence; Chelation; Photochemistry; Stereochemistry; Combinatorial chemistry; Crystallography; Ion; Crystal structure; Physical chemistry; Medicinal chemistry; Inorganic chemistry; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000373767,0.000411902,0.0006751973,0.00004487924,0.0001071083,0.0001018775,0.0005345524,0.0002318345,0.002140388],"category_scores_gemma":[0.0002300836,0.0003788936,0.0001890439,0.0004045106,0.0001165224,0.000239624,0.0001672129,0.0001962077,0.0002106002],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001436635,"about_ca_system_score_gemma":0.0003817661,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000482413,"about_ca_topic_score_gemma":0.00003516523,"domain_scores_codex":[0.9972684,0.00007665437,0.0007333204,0.0006637532,0.0008005628,0.0004573558],"domain_scores_gemma":[0.9980917,0.0001391637,0.0003316318,0.0006667951,0.0004377626,0.0003329516],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002156983,0.000324859,0.000745053,0.0001123627,0.0001046652,0.00005006295,0.0001778667,0.000006439967,0.9965178,0.00005239191,0.001675384,0.000017381],"study_design_scores_gemma":[0.002180301,0.00006805276,0.001174637,0.00008064903,0.000203513,0.00006054569,0.0001391609,0.00006250523,0.9924663,0.0002787809,0.002859149,0.0004263898],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9953877,0.0009323317,0.0002462637,0.0002280795,0.0004821823,0.0001766545,0.0003520324,0.0005271561,0.001667618],"genre_scores_gemma":[0.9970666,0.00004678048,0.001396716,0.0001147656,0.0004549037,0.00002060236,0.0004841808,0.00005681107,0.0003586755],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00405152,"threshold_uncertainty_score":0.9998663,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01614838522480597,"score_gpt":0.2227845421785942,"score_spread":0.2066361569537882,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}