{"id":"W2000125435","doi":"10.1016/j.jasms.2004.02.012","title":"Electrospray/mass spectrometric identification and analysis of 4-hydroxy-2-alkylquinolines (HAQs) produced by <i>Pseudomonas aeruginosa</i>","year":2004,"lang":"en","type":"article","venue":"Journal of the American Society for Mass Spectrometry","topic":"Bacterial Genetics and Biotechnology","field":"Biochemistry, Genetics and Molecular Biology","cited_by":253,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institut National de la Recherche Scientifique","funders":"","keywords":"Chemistry; Electrospray ionization; Alkyl; Side chain; Electrospray; Biosynthesis; Stereochemistry; Mass spectrometry; Degree of unsaturation; Quinoline; Medicinal chemistry; Organic chemistry; Chromatography; Enzyme","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004842289,0.0002108883,0.0005851759,0.0002835394,0.0001027367,0.00003891609,0.0005193742,0.0001425814,0.000002880263],"category_scores_gemma":[0.0001582957,0.0001605434,0.0009939636,0.002628892,0.0004011361,0.00001015367,0.00007954705,0.0002152139,2.199668e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009130583,"about_ca_system_score_gemma":0.0001115754,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001567598,"about_ca_topic_score_gemma":0.000002692114,"domain_scores_codex":[0.9984032,0.00003753848,0.000609173,0.0003339376,0.0002846439,0.000331539],"domain_scores_gemma":[0.9976907,0.00002773076,0.001495443,0.0004470961,0.0002631502,0.00007583165],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001068658,0.0001016393,0.002351223,0.00001719605,0.001826498,2.584254e-7,0.00002017522,0.00005212663,0.9944326,0.000089943,0.0006844664,0.0003170141],"study_design_scores_gemma":[0.0006791049,0.00122598,0.008869505,0.000006905518,0.001010326,0.00002136204,0.0001215204,0.00002753418,0.9862039,0.0005361359,0.00111452,0.0001831993],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9770141,0.002056841,0.01850009,0.001981125,0.0001419263,0.0002024811,0.00008813813,0.000007051292,0.00000826845],"genre_scores_gemma":[0.9809301,0.002894264,0.01564776,0.0002246301,0.0001884953,0.000005664242,0.00002648182,0.00002558775,0.00005697633],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008228688,"threshold_uncertainty_score":0.654677,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004982461746404526,"score_gpt":0.2360917077718118,"score_spread":0.2311092460254073,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}