{"id":"W2000206361","doi":"10.1107/s0108768100008302","title":"Adducts of <i>meso</i> and racemic 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane with trigonally trisubstituted benzene carboxylic acids: supramolecular structures in one and two dimensions","year":2000,"lang":"en","type":"article","venue":"Acta Crystallographica Section B Structural Science","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; University of Guelph","funders":"","keywords":"Chemistry; Supramolecular chemistry; Intramolecular force; Adduct; Hydrogen bond; Intermolecular force; Molecule; Stereochemistry; Benzene; Carboxylic acid; Crystal structure; Crystallography; Medicinal chemistry; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000473697,0.0002156502,0.0001144666,0.00005804066,0.00007813509,0.0001626781,0.0002433535,0.0001706321,0.001880536],"category_scores_gemma":[0.00009418693,0.00008959882,0.00006958817,0.0001209231,0.0001442351,0.0001708664,0.0001390711,0.0002263713,0.0003980436],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002765613,"about_ca_system_score_gemma":0.0001152599,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007530496,"about_ca_topic_score_gemma":0.001615637,"domain_scores_codex":[0.9999279,0.00000895905,0.000003118586,0.00001983904,0.00001995359,0.00002026611],"domain_scores_gemma":[0.9999468,0.000004406988,0.00001942249,0.000004319248,0.000005277845,0.00001978859],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001576161,0.00001083726,0.0001570966,0.00002984727,0.00001007917,0.00003547308,0.00002587442,0.0001990383,0.9977702,0.0002778809,0.0001499613,0.001176107],"study_design_scores_gemma":[0.0000151187,0.0002949859,0.00193599,0.000003435076,0.00001003214,0.0001063495,0.00004194544,0.0007752565,0.9924705,0.00006767065,0.004268195,0.000010476],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9934772,0.0004100736,0.001589627,0.00005064066,0.00003854357,0.00001684751,0.0001840913,0.00008061135,0.00415246],"genre_scores_gemma":[0.9968832,0.0001961608,0.0007535249,0.00004867955,0.000004689977,0.00001131393,0.0002006624,0.00001427795,0.001887501],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001880536,"threshold_uncertainty_score":0.006290972,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009418180250089392,"score_gpt":0.2240221136429414,"score_spread":0.2146039333928521,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}