{"id":"W2000317169","doi":"10.1021/ic048501z","title":"Theoretical and Synthetic Investigations of Carbodiimide Insertions into Al−CH<sub>3</sub> and Al−N(CH<sub>3</sub>)<sub>2</sub> Bonds","year":2005,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Inorganic Chemistry and Materials","field":"Chemistry","cited_by":99,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University; National Institute for Nanotechnology","funders":"","keywords":"Carbodiimide; Chemistry; Steric effects; Alkyl; Insertion reaction; Migratory insertion; Aluminium; Denticity; Crystallography; Stereochemistry; Crystal structure; Polymer chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002361809,0.0004820785,0.0003948661,0.0006129827,0.000553006,0.0004253963,0.001002986,0.0007838876,0.003705152],"category_scores_gemma":[0.0006551741,0.0003305461,0.0005032317,0.0004342774,0.000613108,0.0005636641,0.0002121965,0.0004317058,0.0003161736],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001088234,"about_ca_system_score_gemma":0.0007698187,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003779869,"about_ca_topic_score_gemma":0.003104551,"domain_scores_codex":[0.9999021,0.00001266004,0.000002594327,0.000009543328,0.00003995233,0.00003307398],"domain_scores_gemma":[0.9997432,0.0001446966,0.00003233708,0.00001918139,0.00004409203,0.00001654792],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"theoretical_or_conceptual","study_design_scores_codex":[0.0000883019,0.0001735237,0.001800655,0.0006571907,0.00002616734,0.0004541062,0.0001424152,0.8402622,0.01944557,0.1248122,0.0006069228,0.01153063],"study_design_scores_gemma":[0.00002172057,0.00005713158,0.0005752349,0.00001820039,0.00001089179,0.00005931386,0.00006645935,0.9840726,0.004118728,0.01003773,0.0009522606,0.00000971567],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8415438,0.002004704,0.04164572,0.0007397985,0.00006986003,0.0001044027,0.0003729147,0.0001292891,0.1133895],"genre_scores_gemma":[0.9854116,0.0009400458,0.01074803,0.00006007337,0.00001490256,0.00009906503,0.0001528328,0.00003083172,0.002542478],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003779869,"threshold_uncertainty_score":0.01239496,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005467330756790015,"score_gpt":0.2072642307852217,"score_spread":0.2017969000284316,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}