{"id":"W2000335063","doi":"10.1139/v08-114","title":"Octahedral perfluoroalkyl complexes of Ir(III) formed by oxidative addition of perfluoroalkyl iodides to Ir(acac)(CO)<sub>2</sub>","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Science Foundation","keywords":"Chemistry; Iridium; Trifluoromethanesulfonate; Octahedron; Oxidative addition; Ligand (biochemistry); Density functional theory; Medicinal chemistry; Natural bond orbital; Infrared spectroscopy; Acceptor; Crystallography; Stereochemistry; Computational chemistry; Catalysis; Organic chemistry; Crystal structure","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008999511,0.0003429551,0.0001903157,0.0001036212,0.0001211522,0.0002747762,0.0003212316,0.0002791372,0.002665039],"category_scores_gemma":[0.0001645517,0.0001481841,0.0001201619,0.0001120635,0.0001743595,0.0001894092,0.0002609257,0.0003774972,0.0005390358],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002850748,"about_ca_system_score_gemma":0.0001538015,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007353237,"about_ca_topic_score_gemma":0.001668051,"domain_scores_codex":[0.9999152,0.00001044041,0.000005108077,0.00001362316,0.00002615499,0.00002940494],"domain_scores_gemma":[0.9999324,0.000008903115,0.00003135576,0.00000551328,0.000009243474,0.00001249706],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002335136,0.00002797481,0.0002194073,0.0001436293,0.00001076106,0.000141311,0.0000660179,0.0003304158,0.9949632,0.0009166466,0.0002793228,0.002667853],"study_design_scores_gemma":[0.00002560783,0.0002423427,0.0005222157,0.000005472403,0.00001189672,0.0001914925,0.00003291559,0.0007692423,0.9951667,0.00008759846,0.002936933,0.000007570477],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9873729,0.0004924953,0.003954019,0.00007318424,0.00003952876,0.00004549937,0.0002330777,0.0001688657,0.007620445],"genre_scores_gemma":[0.9923115,0.0003126193,0.003404778,0.00004361049,0.00000796515,0.0000306408,0.0003066706,0.00004299825,0.003539201],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002665039,"threshold_uncertainty_score":0.008915484,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.045999732289917,"score_gpt":0.3259383044992889,"score_spread":0.2799385722093719,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}