{"id":"W2000436703","doi":"10.1002/ejic.201300152","title":"Acetonitrile Coupling at an Electron‐Rich Iridium Center Supported by a PCP Pincer Ligand","year":2013,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Heterolysis; Acetonitrile; Iridium; Pincer ligand; Pincer movement; Ligand (biochemistry); Carbene; Moiety; Photochemistry; Medicinal chemistry; Bridging ligand; Crystallography; Stereochemistry; Crystal structure; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004341485,0.0003766313,0.0005063147,0.00004488444,0.0001757022,0.0001810233,0.0008947322,0.00008518909,0.08321456],"category_scores_gemma":[0.0001123524,0.0003402822,0.0002548695,0.0002264277,0.00008968284,0.0002925772,0.0002431643,0.0005619325,0.0003524746],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002907455,"about_ca_system_score_gemma":0.0001110478,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005282738,"about_ca_topic_score_gemma":7.918824e-7,"domain_scores_codex":[0.9975706,0.00003930543,0.000959011,0.0004003164,0.0004895745,0.0005412139],"domain_scores_gemma":[0.9977959,0.00005817664,0.0007713767,0.0006301164,0.0002898668,0.0004545474],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003534704,0.0002661021,0.00113536,0.00007007725,0.0002189298,0.00005957917,0.0001471591,0.000002742644,0.9854023,1.872134e-7,0.01175975,0.0009024783],"study_design_scores_gemma":[0.0009566917,0.00004175714,0.0004556941,0.0000602186,0.0001057626,0.0005315488,0.0002735481,0.00006023809,0.9548537,0.000003886752,0.04228706,0.0003699548],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9842107,0.0009647163,0.0000302528,0.0002233135,0.000061472,0.00003866952,0.00003521202,0.00005581661,0.01437981],"genre_scores_gemma":[0.9876681,0.0001687418,0.0000856881,0.00009086536,0.0007710331,0.000001705342,0.00009431555,0.0001223547,0.01099721],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08286209,"threshold_uncertainty_score":0.9999049,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007976655070187685,"score_gpt":0.201831564009013,"score_spread":0.1938549089388253,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}