{"id":"W2000546722","doi":"10.1002/chin.200420082","title":"Microwave‐Assisted Pericyclic Reactions in Cascade to Construct Decalin Frameworks Possessing Quaternary Centers. Scope and Limitations.","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Pericyclic reaction; Chemistry; Decalin; Scope (computer science); Construct (python library); Cascade; Combinatorial chemistry; Organic chemistry; Chromatography; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005504649,0.0001997658,0.0002270282,0.00009316651,0.0001510663,0.0001073943,0.000135651,0.0003597688,0.0001543449],"category_scores_gemma":[0.000314359,0.0001923754,0.00008281157,0.000251308,0.0001313481,0.0001950977,0.00007794009,0.0005444922,0.00002562239],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003522951,"about_ca_system_score_gemma":0.00007393883,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002914121,"about_ca_topic_score_gemma":0.0001548268,"domain_scores_codex":[0.9988236,6.462905e-7,0.00042401,0.000290234,0.0001377586,0.0003237201],"domain_scores_gemma":[0.999202,0.0001754892,0.0001080867,0.0002529509,0.0000402237,0.000221298],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003336,0.0001387981,0.0009350481,0.0001033924,0.00003144611,0.00001817783,0.0007667443,0.000006092697,0.7695886,0.00007635396,0.000339837,0.2279622],"study_design_scores_gemma":[0.0006970939,0.000007942162,0.002814537,0.0006934284,0.00002802826,0.0003358744,0.001396783,0.00003536438,0.9787115,0.000192001,0.01474239,0.000344992],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8323207,0.000194861,0.00003782127,0.0009097995,0.00007283669,0.00008364004,0.00001159868,0.00007733019,0.1662914],"genre_scores_gemma":[0.9959422,0.0001935075,0.002514052,0.0002647823,0.0001014187,0.00003472891,0.00004044305,0.00002460714,0.0008842581],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2276172,"threshold_uncertainty_score":0.784484,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0225161603909616,"score_gpt":0.2649910586064619,"score_spread":0.2424748982155003,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}