{"id":"W2000581611","doi":"10.1016/j.ica.2005.06.064","title":"Kinetic studies of the reduction of hexaaquacobalt(III) perchlorate by a cobaloxime, [Co(dmgBF2)2(H2O)2]","year":2005,"lang":"en","type":"article","venue":"Inorganica Chimica Acta","topic":"Porphyrin Metabolism and Disorders","field":"Biochemistry, Genetics and Molecular Biology","cited_by":6,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Reaction rate constant; Perchlorate; Kinetic energy; Hydrolysis; Saturation (graph theory); Kinetics; Medicinal chemistry; Constant (computer programming); Order (exchange); Inorganic chemistry; Physical chemistry; Analytical Chemistry (journal); Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000434253,0.0002954928,0.0005349802,0.0001809906,0.0002158241,0.000494311,0.0006977561,0.000514646,0.001453841],"category_scores_gemma":[0.0007070097,0.0002164776,0.000254145,0.0003054558,0.0002834228,0.0003698753,0.0002090421,0.0006040331,0.0004835141],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008016363,"about_ca_system_score_gemma":0.0003711007,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.008117169,"about_ca_topic_score_gemma":0.004263614,"domain_scores_codex":[0.999701,0.00004316521,0.00002376106,0.0000501278,0.00008171188,0.0001002276],"domain_scores_gemma":[0.9996237,0.0001386522,0.00004336966,0.00004761136,0.00009909915,0.00004752191],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001565134,0.000189845,0.0008642824,0.0001773692,0.00006082857,0.0000969451,0.0001438103,0.00114118,0.9897719,0.0007408453,0.0003964191,0.004851334],"study_design_scores_gemma":[0.00007753754,0.0003357732,0.002297769,0.000007212941,0.0000246762,0.0001089647,0.00006799128,0.01106736,0.9842404,0.0001073172,0.001640584,0.0000244689],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9912376,0.001138615,0.004094401,0.0002087987,0.00005251816,0.00004565229,0.0005274933,0.0001487028,0.002546249],"genre_scores_gemma":[0.9957872,0.0003008893,0.001358771,0.00002024361,0.000005882519,0.00001533917,0.0003286321,0.00002035368,0.00216255],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008117169,"threshold_uncertainty_score":0.01613986,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01096640790932256,"score_gpt":0.2635943159750553,"score_spread":0.2526279080657327,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}