{"id":"W2000781248","doi":"10.1021/la0266740","title":"Dynamic Surface Excesses of Fluorocarbon Surfactants","year":2003,"lang":"en","type":"article","venue":"Langmuir","topic":"Surfactants and Colloidal Systems","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Canadian Celiac Association","keywords":"Fluorocarbon; Surface tension; Dynamic light scattering; Pulmonary surfactant; Critical micelle concentration; Gibbs isotherm; Chemistry; Adsorption; Drop (telecommunication); Analytical Chemistry (journal); Aqueous solution; Micelle; Thermodynamics; Chromatography; Materials science; Physical chemistry; Organic chemistry; Nanotechnology; Physics; Nanoparticle","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001200945,0.0001556939,0.0002757543,0.00001834116,0.00005110548,0.00001896238,0.0001720634,0.0001133127,0.001197623],"category_scores_gemma":[0.0000447758,0.0001356015,0.00007540386,0.0001616852,0.00003632122,0.00006220239,0.00002014401,0.00009345444,0.00004248358],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003974152,"about_ca_system_score_gemma":0.00003798369,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001986413,"about_ca_topic_score_gemma":0.00005398819,"domain_scores_codex":[0.9989858,0.0000282713,0.0002668231,0.0002164162,0.0002448688,0.000257856],"domain_scores_gemma":[0.9994081,0.00007094842,0.0001277458,0.0002833887,0.00005041514,0.00005938147],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003102264,0.0001264499,0.07100939,0.0003290952,0.00008154965,0.00002022883,0.0003581314,0.00006090831,0.9261344,0.0007547575,0.0002942938,0.0007997631],"study_design_scores_gemma":[0.001393098,0.00004526852,0.01358186,0.0001965893,0.00005894021,0.00004405541,0.001764661,0.0005461942,0.9244434,0.0004837785,0.05669237,0.0007497561],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.887038,0.0008834171,0.00001082199,0.00001529885,0.0001264189,0.00003904706,0.00003658323,0.00007314005,0.1117773],"genre_scores_gemma":[0.9943489,0.00003256137,0.0001492908,0.00001164634,0.00001355701,0.000002705604,0.000008786874,0.00002771275,0.005404835],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1073109,"threshold_uncertainty_score":0.9997154,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008456154448920948,"score_gpt":0.2249025649879757,"score_spread":0.2164464105390548,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}