{"id":"W2000820270","doi":"10.1021/ol702703b","title":"Nonplanar Aromatic Compounds. 9. Synthesis, Structure, and Aromaticity of 1:2,13:14-Dibenzo[2]paracyclo[2](2,7)- pyrenophane-1,13-diene","year":2007,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":50,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Aromaticity; Chemistry; Diene; Computational chemistry; Stereochemistry; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005156082,0.0005078021,0.0008595025,0.0001622604,0.0002205424,0.00009599989,0.0006301581,0.0002077075,0.001459959],"category_scores_gemma":[0.0003562821,0.0004458797,0.0001458591,0.0002279487,0.0003352484,0.0002029472,0.0001769582,0.0002964046,0.00003403511],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001356126,"about_ca_system_score_gemma":0.00005006586,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002724963,"about_ca_topic_score_gemma":0.000168173,"domain_scores_codex":[0.9970816,0.00005831311,0.001016448,0.0005480932,0.0006189229,0.0006765807],"domain_scores_gemma":[0.9971922,0.001115854,0.0005061668,0.0008958155,0.00004402722,0.0002459132],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007973606,0.0001104624,0.006599647,0.0006084045,0.0002416763,0.00003762812,0.0007281277,0.000004307878,0.9858882,0.00001327991,0.001796541,0.003891924],"study_design_scores_gemma":[0.0007693291,0.00004416297,0.01762082,0.0004607882,0.0002251639,0.0002017998,0.0004026805,0.0001374807,0.9781446,0.0007918525,0.0005262346,0.0006750689],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9955215,0.0004749238,0.0001804465,0.0008369071,0.000186931,0.000145907,0.00004261436,0.0001469396,0.002463791],"genre_scores_gemma":[0.9965457,0.00004656296,0.002428601,0.0006095266,0.0001952682,0.000007254528,0.00002113165,0.00008661853,0.00005939226],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01102117,"threshold_uncertainty_score":0.9997993,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008969129142344132,"score_gpt":0.2009492658619873,"score_spread":0.1919801367196432,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}