{"id":"W2001003327","doi":"10.1021/cg030016b","title":"A New Bridging Chelating Ligand for Crystal Engineering:  Synthesis, Polymorphism, and Two Modes of Assembly of 1,4-Bis(3-phenyl-1,3-propanedion)benzene with Metal Cations Resulting in Either Discrete or Polymeric Complexes","year":2003,"lang":"en","type":"article","venue":"Crystal Growth & Design","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":48,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"","keywords":"Chemistry; Ligand (biochemistry); Crystallography; Stereochemistry; Bridging ligand; Chelation; Alkane stereochemistry; Metal; Crystal structure; Crystal engineering; Phenylene; Ring (chemistry); Supramolecular chemistry; Polymer; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006854637,0.0002126151,0.0001427963,0.0001108158,0.0001361442,0.0002462683,0.0003221253,0.0001759735,0.0007130805],"category_scores_gemma":[0.000099661,0.0001295512,0.000088038,0.0001101736,0.0001407844,0.000201284,0.0002137389,0.0003185882,0.000277509],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003553443,"about_ca_system_score_gemma":0.000242955,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006723942,"about_ca_topic_score_gemma":0.001641067,"domain_scores_codex":[0.9999439,0.000008497906,0.000004355075,0.00001457164,0.00001604055,0.00001262385],"domain_scores_gemma":[0.9999413,0.000007163175,0.00001638943,0.000007027756,0.000006647131,0.00002150485],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002769984,0.00001496775,0.0001036953,0.00003604711,0.000001734702,0.00002830498,0.00001827373,0.0001541278,0.9969934,0.0002780819,0.00003737734,0.002306206],"study_design_scores_gemma":[0.0000273752,0.0001042173,0.0003856961,0.000004021075,0.000007448055,0.0001998745,0.00001800786,0.001157172,0.9937754,0.00004499393,0.004268386,0.00000736915],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9788052,0.0005508817,0.01821415,0.0001312232,0.00001331982,0.00004391804,0.0001599277,0.000217583,0.001863763],"genre_scores_gemma":[0.9689478,0.0003353408,0.02725154,0.00005956513,0.000006910503,0.00005448901,0.0002121782,0.00005290774,0.00307918],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007130805,"threshold_uncertainty_score":0.002578259,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02450621308032047,"score_gpt":0.2444688390715584,"score_spread":0.2199626259912379,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}