{"id":"W2001124516","doi":"10.1021/ol800747v","title":"Catalytic Enantioselective Addition of Diorganozinc Reagents to Vinyl Sulfones","year":2008,"lang":"en","type":"article","venue":"Organic Letters","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":54,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Reagent; Chemistry; Enantioselective synthesis; Conjugate; Catalysis; BINAP; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00007004362,0.0001649658,0.0002761722,0.0001488207,0.0001040168,0.000008614353,0.0002538513,0.0000738811,0.001242453],"category_scores_gemma":[0.000170121,0.0001574494,0.0001127755,0.0007371041,0.00006001578,0.00009597167,0.00006461847,0.00009304309,0.0003033236],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001615164,"about_ca_system_score_gemma":0.00005177548,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001163363,"about_ca_topic_score_gemma":0.00001381284,"domain_scores_codex":[0.9988164,0.0000151751,0.000278038,0.000321909,0.0003137634,0.0002546876],"domain_scores_gemma":[0.9992061,0.00008896438,0.0001385067,0.0004074216,0.00006125917,0.000097765],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001661646,0.00007343239,0.003162768,0.00002415114,0.0001225681,0.0000240671,0.0005679753,0.000001039658,0.9756983,0.000005762081,0.01249924,0.00780409],"study_design_scores_gemma":[0.0002291733,0.0000167128,0.007509587,0.0000218726,0.00007336325,0.00003315574,0.0001905507,0.000002325463,0.9906899,0.000003478554,0.001043937,0.0001859604],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966754,0.00004632791,0.0003424478,0.0007366274,0.00005726067,0.00005843717,0.00005197923,0.00006039151,0.001971094],"genre_scores_gemma":[0.9988471,0.00003045769,0.000114173,0.0004416253,0.0001472844,0.0000115811,0.0000707302,0.00003821199,0.0002988504],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01499159,"threshold_uncertainty_score":0.9996706,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009594868547366513,"score_gpt":0.1959293640737388,"score_spread":0.1863344955263722,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}