{"id":"W2001143903","doi":"10.1021/ol8026957","title":"Synthesis of Pyrrolnitrin and Related Halogenated Phenylpyrroles","year":2009,"lang":"en","type":"article","venue":"Organic Letters","topic":"Vanadium and Halogenation Chemistry","field":"Chemistry","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Natural product; Nitrobenzene; Antifungal; Organic chemistry; Product (mathematics); Combinatorial chemistry; Stereochemistry; Microbiology; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001654835,0.0003094816,0.0002589829,0.0001875174,0.000183793,0.0001933945,0.0003507087,0.0002750068,0.001765477],"category_scores_gemma":[0.0001307178,0.0001933938,0.0002040669,0.0002180811,0.0001620702,0.0002878818,0.0002379443,0.0003914678,0.0005802717],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003663558,"about_ca_system_score_gemma":0.0002793462,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004097793,"about_ca_topic_score_gemma":0.0009470423,"domain_scores_codex":[0.9998809,0.0000159037,0.00001151616,0.00002368442,0.00004144293,0.0000264509],"domain_scores_gemma":[0.9999459,0.00000692,0.00001306737,0.000008964989,0.00001007045,0.00001506305],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009208517,0.00004029611,0.00006453225,0.0001615259,0.000008797774,0.0002224125,0.00005189428,0.0006072784,0.9901153,0.001362839,0.0001881567,0.007084812],"study_design_scores_gemma":[0.00003402536,0.0004738588,0.0006057369,0.000006885977,0.00001242862,0.0003643951,0.00001642242,0.0006924722,0.9834033,0.0002138001,0.01416487,0.00001188599],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9349221,0.008818238,0.03467799,0.0003251946,0.0002275784,0.0004373781,0.00139423,0.0004087298,0.01878862],"genre_scores_gemma":[0.956812,0.006052285,0.02619635,0.00009655474,0.00002752266,0.0001564704,0.0007560444,0.00004114348,0.009861704],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001765477,"threshold_uncertainty_score":0.005906165,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005017580529956137,"score_gpt":0.1880665849061307,"score_spread":0.1830490043761745,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}