{"id":"W2001207692","doi":"10.1063/1.3697869","title":"Nonpolar nitrous oxide dimer: Observation of combination bands of (14N2O)2 and (15N2O)2 involving the torsion and antigeared bending modes","year":2012,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Spectroscopy and Laser Applications","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"Natural Resources Canada; University of Calgary","funders":"","keywords":"Intermolecular force; Ab initio quantum chemistry methods; Dimer; Chemistry; Atomic physics; Ab initio; Spectral line; Molecular physics; Analytical Chemistry (journal); Molecule; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003102242,0.00007917716,0.0001681347,0.00001329502,0.00007037658,0.000009400802,0.0001353361,0.00004907596,0.000004973476],"category_scores_gemma":[0.00005303419,0.00005098155,0.00004396004,0.00009634941,0.0001267738,0.0002264374,0.00004954612,0.0002045883,1.404656e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002495702,"about_ca_system_score_gemma":0.00001231135,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000251229,"about_ca_topic_score_gemma":2.7259e-7,"domain_scores_codex":[0.9993567,0.00002241408,0.0002865992,0.00004769623,0.0001818023,0.0001047592],"domain_scores_gemma":[0.999065,0.000244539,0.0004130541,0.0001350352,0.0001001219,0.00004220684],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004471097,0.00009212692,0.01630359,0.00005231951,0.00003282577,3.033918e-8,0.0008499744,0.0000114582,0.9798205,0.002540426,0.00004073129,0.0002113198],"study_design_scores_gemma":[0.0002985944,0.00001654428,0.003871944,0.00007613654,0.00008378331,0.000006980562,0.0003750537,0.001498316,0.9870073,0.006693025,0.00002056468,0.00005175601],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979367,0.001053526,0.0006739703,0.0001260163,0.00001448146,0.00003591439,0.000004932923,0.00000423355,0.0001501947],"genre_scores_gemma":[0.9993089,0.0002350293,0.0003008328,0.00001948581,0.0001151656,9.926193e-7,0.00000467658,0.000008879612,0.000006064969],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01243165,"threshold_uncertainty_score":0.2078967,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01754049596987153,"score_gpt":0.2470336815799263,"score_spread":0.2294931856100547,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}