{"id":"W2001266804","doi":"10.1002/rcm.221","title":"Ion fragmentation in an electrospray ionization mass spectrometer interface with different gases","year":2001,"lang":"en","type":"article","venue":"Rapid Communications in Mass Spectrometry","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Fragmentation (computing); Chemistry; Krypton; Argon; Mass spectrometry; Ion; Body orifice; Ionization; Condensation; Analytical Chemistry (journal); Ion source; Chromatography; Thermodynamics; Physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0009339587,0.0008733972,0.0005969933,0.001090235,0.0006564498,0.0004559972,0.0009512156,0.0009622304,0.001832939],"category_scores_gemma":[0.00101325,0.0002955593,0.000421682,0.001037577,0.0004188907,0.00110557,0.0004636172,0.0008343482,0.0005391201],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005248069,"about_ca_system_score_gemma":0.000439356,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001042434,"about_ca_topic_score_gemma":0.0008794093,"domain_scores_codex":[0.9992962,0.00007103621,0.00003399291,0.0001741052,0.0003504386,0.0000742703],"domain_scores_gemma":[0.9992749,0.0002470711,0.0001526826,0.00004217627,0.0002012739,0.00008180294],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003046873,0.00005088637,0.0007007687,0.00008614425,0.0000338762,0.0003181444,0.0000741832,0.0002629804,0.9938101,0.0002847743,0.0002521498,0.003821217],"study_design_scores_gemma":[0.00008353576,0.0005253968,0.004225145,0.00001999174,0.00003641894,0.001149626,0.00007131182,0.004788629,0.9870368,0.0002863471,0.001749432,0.00002723657],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9382184,0.002664513,0.05195336,0.0003017949,0.0001763032,0.0002251441,0.0008331665,0.001348052,0.004279234],"genre_scores_gemma":[0.9182189,0.003511624,0.06943543,0.0005519338,0.00009030843,0.0003957389,0.001514061,0.0002830768,0.005998915],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001832939,"threshold_uncertainty_score":0.006131768,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01981645005459538,"score_gpt":0.2963146036015151,"score_spread":0.2764981535469197,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}