{"id":"W2001383095","doi":"10.1016/j.ica.2005.04.046","title":"Structural diversity of cadmium(II) complexes of tetraorganodichalcogenoimidodiphosphinato ligands: Monomeric Cd[(SPMe2)2N]2, dinuclear [Cd{(OPMe2)(SPPh2)N}2]2 and [Cd2{(OPPh2)2N}4(H2O)], and trinuclear K[Cd2{(OPPh2)2N}5]","year":2005,"lang":"en","type":"article","venue":"Inorganica Chimica Acta","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Crystallography; Octahedron; Ligand (biochemistry); Trigonal bipyramidal molecular geometry; Dimer; Bimetallic strip; Molecule; Monomer; Tetramer; Pentagonal bipyramidal molecular geometry; Bipyramid; Square pyramidal molecular geometry; Stereochemistry; Crystal structure; Nuclear magnetic resonance spectroscopy; Metal; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009832014,0.0001636194,0.0001463602,0.0001534266,0.0001886792,0.0002839778,0.0003064551,0.00016336,0.00138576],"category_scores_gemma":[0.0001725155,0.0001561114,0.00005189453,0.0001303423,0.0001587335,0.0001631908,0.0002405254,0.0001850644,0.0001874836],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000263986,"about_ca_system_score_gemma":0.0001552507,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004908312,"about_ca_topic_score_gemma":0.00128345,"domain_scores_codex":[0.9999179,0.00001442773,0.000007185537,0.00002285206,0.0000207061,0.0000169969],"domain_scores_gemma":[0.9999273,0.00001684743,0.00000866909,0.000009859556,0.00001581043,0.00002144834],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001665823,0.00001362411,0.0004517932,0.00004552296,0.000005326061,0.00002736583,0.00003940485,0.0001943596,0.9972257,0.0001944916,0.00006438449,0.001571344],"study_design_scores_gemma":[0.00002411422,0.000122431,0.002083577,0.000003605845,0.00001399297,0.0001712089,0.00004867881,0.0008275899,0.9942836,0.00006609978,0.00235001,0.000005089296],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.997314,0.0001769953,0.0004860218,0.00002211117,0.000003640196,0.0000052909,0.00006153221,0.00003660263,0.001893619],"genre_scores_gemma":[0.9982998,0.0000872156,0.0004481176,0.00001969664,0.000001058266,0.000007513813,0.0001737729,0.000009582199,0.0009532243],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00138576,"threshold_uncertainty_score":0.004635811,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01193296977799096,"score_gpt":0.2002173390994616,"score_spread":0.1882843693214706,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}