{"id":"W2001383095","doi":"10.1016/j.ica.2005.04.046","title":"Structural diversity of cadmium(II) complexes of tetraorganodichalcogenoimidodiphosphinato ligands: Monomeric Cd[(SPMe2)2N]2, dinuclear [Cd{(OPMe2)(SPPh2)N}2]2 and [Cd2{(OPPh2)2N}4(H2O)], and trinuclear K[Cd2{(OPPh2)2N}5]","year":2005,"lang":"en","type":"article","venue":"Inorganica Chimica Acta","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Crystallography; Octahedron; Ligand (biochemistry); Trigonal bipyramidal molecular geometry; Dimer; Bimetallic strip; Molecule; Monomer; Tetramer; Pentagonal bipyramidal molecular geometry; Bipyramid; Square pyramidal molecular geometry; Stereochemistry; Crystal structure; Nuclear magnetic resonance spectroscopy; Metal; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002750464,0.0008196115,0.001429563,0.000300716,0.0008359274,0.000140231,0.001036724,0.0004740115,0.003380687],"category_scores_gemma":[0.0002117816,0.0008260011,0.0002762578,0.0005917819,0.0007108081,0.0006615922,0.002020824,0.0006051375,0.0000185389],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002208453,"about_ca_system_score_gemma":0.0001400816,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001731691,"about_ca_topic_score_gemma":0.00006722866,"domain_scores_codex":[0.9959694,0.00006956782,0.001338021,0.001127048,0.0007226879,0.0007732939],"domain_scores_gemma":[0.9969479,0.0002627476,0.001035076,0.001038441,0.0002360817,0.0004797041],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002571442,0.0003614871,0.01665439,0.0003595686,0.0003996184,0.000004721913,0.003486859,0.000001484965,0.9763045,0.0001785723,0.0002002282,0.001791366],"study_design_scores_gemma":[0.002693525,0.0003126074,0.1438022,0.0002064837,0.0005684798,0.00015815,0.001042722,0.0003835448,0.8416035,0.0002141962,0.00772647,0.00128807],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961499,0.0005091089,0.000002596263,0.001018793,0.0001333474,0.0002993606,0.0004111615,0.0001952898,0.001280423],"genre_scores_gemma":[0.9973727,0.001151741,0.0004236664,0.0001460942,0.0002920982,0.000005662649,0.0001086067,0.0001591274,0.0003402611],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.134701,"threshold_uncertainty_score":0.9994191,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01193296977799096,"score_gpt":0.2002173390994616,"score_spread":0.1882843693214706,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}