{"id":"W2001496288","doi":"10.1021/ja8062277","title":"New Cationic and Zwitterionic Cp*M(κ<sup>2</sup>-P,S) Complexes (M = Rh, Ir): Divergent Reactivity Pathways Arising from Alternative Modes of Ancillary Ligand Participation in Substrate Activation","year":2008,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":64,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; Dalhousie University","funders":"","keywords":"Chemistry; Adduct; Reactivity (psychology); Ligand (biochemistry); Indene; Lewis acids and bases; Cationic polymerization; Yield (engineering); Stereochemistry; Medicinal chemistry; Zwitterion; Molecule; Catalysis; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001676294,0.0005211373,0.000208816,0.0001843954,0.0001736725,0.0005286373,0.0005846334,0.0003239349,0.001526924],"category_scores_gemma":[0.0002670461,0.0001985057,0.0001228306,0.0002152753,0.0003040791,0.000452924,0.0005412999,0.0004677182,0.0004720996],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002879951,"about_ca_system_score_gemma":0.0001485667,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003371687,"about_ca_topic_score_gemma":0.0006675056,"domain_scores_codex":[0.9998804,0.00001662927,0.000008323849,0.0000283004,0.00003412937,0.00003214988],"domain_scores_gemma":[0.9999381,0.000008169935,0.0000213693,0.000006282647,0.000008262581,0.00001783358],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002222275,0.00002579953,0.0002018811,0.0001732133,0.00001401512,0.0002190047,0.0001060388,0.0002206638,0.9903509,0.001465933,0.0004160103,0.006584273],"study_design_scores_gemma":[0.00003338257,0.0003662689,0.0006262767,0.000009159752,0.00001569278,0.000752517,0.00004887403,0.0007202763,0.9905477,0.0001760527,0.006685963,0.00001770164],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9721788,0.001933898,0.01010533,0.0001474227,0.00005439632,0.0001067298,0.0002446508,0.0004072754,0.01482154],"genre_scores_gemma":[0.990796,0.0005583012,0.004694918,0.00005315449,0.00001422497,0.00004557893,0.0001815317,0.00004689901,0.003609371],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001526924,"threshold_uncertainty_score":0.005108058,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02822410332136158,"score_gpt":0.2469206926314563,"score_spread":0.2186965893100948,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}