{"id":"W2001514395","doi":"10.1039/c5ra01728a","title":"The determination of ligand shell composition of bifunctional alkanethiol-capped gold nanoparticles using GC/MS/MS","year":2015,"lang":"en","type":"article","venue":"RSC Advances","topic":"Gold and Silver Nanoparticles Synthesis and Applications","field":"Materials Science","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"Sackville Memorial Hospital; Mount Allison University","funders":"Natural Sciences and Engineering Research Council of Canada; New Brunswick Innovation Foundation","keywords":"Bifunctional; Colloidal gold; Chemistry; Ligand (biochemistry); Nanoparticle; Shell (structure); Gas chromatography–mass spectrometry; Chromatography; Nanotechnology; Mass spectrometry; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000407713,0.0008763282,0.0002861128,0.000958822,0.0003734261,0.0004299962,0.0005520615,0.0007347098,0.001113158],"category_scores_gemma":[0.0007294985,0.0002935435,0.0001984425,0.0002904177,0.0004178074,0.000338806,0.0003202421,0.00053826,0.0007737553],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006242888,"about_ca_system_score_gemma":0.0004122816,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001298763,"about_ca_topic_score_gemma":0.003198525,"domain_scores_codex":[0.9994752,0.00004872771,0.00003299221,0.0001824542,0.0002187773,0.00004186458],"domain_scores_gemma":[0.9996923,0.0000728974,0.00004783793,0.00004210207,0.0001113156,0.0000336526],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002038288,0.000006558297,0.0001234582,0.0000193989,0.000003465515,0.00001316122,0.00001092338,0.00004551827,0.9978867,0.00003618326,0.00003705963,0.001797304],"study_design_scores_gemma":[0.0000014728,0.00002659481,0.0006054798,0.000003082697,0.000005056913,0.00005380543,0.00001071511,0.001773567,0.997093,0.00003934159,0.0003832336,0.000004640307],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8565321,0.002500226,0.1292408,0.00035482,0.0002181698,0.0002031306,0.002486277,0.002657707,0.005806722],"genre_scores_gemma":[0.8861535,0.001217638,0.1038515,0.0002849209,0.00003411229,0.0002077572,0.001361362,0.0002212203,0.006667993],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001298763,"threshold_uncertainty_score":0.004529536,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03402951812278426,"score_gpt":0.2788211788996973,"score_spread":0.2447916607769131,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}