{"id":"W2001524468","doi":"10.1039/b107164p","title":"7 Reaction mechanisms. Part (iv) Radical and radical ion reactions","year":2001,"lang":"en","type":"article","venue":"Annual Reports Section B (Organic Chemistry)","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Ion; Chemistry; Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004039777,0.0004859574,0.0004679293,0.00007540109,0.0004950314,0.0001008702,0.0001720011,0.0008459074,0.01147621],"category_scores_gemma":[0.001517031,0.0005239598,0.0002294334,0.0005374334,0.0003459895,0.0004540496,0.0001185544,0.001316191,0.00004745919],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006409056,"about_ca_system_score_gemma":0.0002090166,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003367428,"about_ca_topic_score_gemma":0.00002020504,"domain_scores_codex":[0.9961594,0.00003254171,0.001121085,0.001200032,0.0008152694,0.0006717244],"domain_scores_gemma":[0.9973874,0.000205607,0.0005467808,0.0008709534,0.0001754204,0.0008138172],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007946449,0.0003339171,0.0002296454,0.00008391422,0.00008446614,0.0003639644,0.00006536447,0.000002013199,0.9905297,0.00008199782,0.006861719,0.001283839],"study_design_scores_gemma":[0.0004470521,0.0000266578,0.0001996792,0.00008136612,0.0001025337,0.01110627,0.0002562641,0.0000753544,0.5148525,0.002002713,0.4703859,0.00046372],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9338506,0.0001410666,0.001423994,0.001729203,0.001122482,0.0002533024,0.00003205343,0.001127861,0.06031942],"genre_scores_gemma":[0.9702534,0.0004922173,0.0002172621,0.0001446254,0.002115351,0.0001143018,0.000264287,0.0001152855,0.02628326],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4756772,"threshold_uncertainty_score":0.9997212,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008624584016156192,"score_gpt":0.2316326051649631,"score_spread":0.2230080211488069,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}