{"id":"W2001547945","doi":"10.1088/0953-8984/25/8/085505","title":"L<sub>2,3</sub>-edge x-ray absorption near-edge spectroscopy analysis of photoisomerism in solid ruthenium–sulfur dioxide complexes","year":2013,"lang":"en","type":"article","venue":"Journal of Physics Condensed Matter","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"Royal Society; Diamond Light Source","keywords":"Absorption spectroscopy; Spectroscopy; Trifluoromethanesulfonate; Ruthenium; Chemistry; Absorption (acoustics); Photochemistry; Photoisomerization; Absorption edge; Crystallography; Inorganic chemistry; Analytical Chemistry (journal); Materials science; Isomerization; Band gap; Catalysis; Optics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000105919,0.0001726991,0.0001534283,0.0002132457,0.0001286245,0.0002373948,0.0002120966,0.0003003167,0.001623704],"category_scores_gemma":[0.0001575647,0.0001459437,0.0001260288,0.0001478015,0.0002439521,0.0001611785,0.0001221925,0.000293663,0.0001940164],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001510615,"about_ca_system_score_gemma":0.00008175692,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000325322,"about_ca_topic_score_gemma":0.0003666659,"domain_scores_codex":[0.999894,0.00003003592,0.000006350704,0.00001682687,0.00003206312,0.0000206984],"domain_scores_gemma":[0.9998947,0.00002834899,0.00003451347,0.000007894153,0.00002131659,0.0000130514],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001268106,0.000007940717,0.0003406802,0.00001997035,0.000004502871,0.00002230962,0.00002083646,0.00008125913,0.9985024,0.00005205094,0.00002878057,0.0007925809],"study_design_scores_gemma":[0.000007789387,0.0001962334,0.008003307,0.000002896808,0.000009422168,0.0001295066,0.00004964677,0.0009536321,0.9901842,0.0000445783,0.0004138602,0.000004851199],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9974046,0.0002605668,0.001032274,0.00003720742,0.000003242735,0.000005742885,0.00007014017,0.00004341803,0.001142782],"genre_scores_gemma":[0.9981659,0.00009119589,0.0008678104,0.00002878865,0.00000224434,0.000006537867,0.0001212501,0.00001475229,0.0007015406],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001623704,"threshold_uncertainty_score":0.005431771,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02236729587787347,"score_gpt":0.2598927944193702,"score_spread":0.2375254985414968,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}