{"id":"W2001580148","doi":"10.1021/ic700877n","title":"Luminescent Platinum(II) Complexes Containing Isoquinolinyl Indazolate Ligands:  Synthetic Reaction Pathway and Photophysical Properties","year":2007,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":80,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"","keywords":"Chemistry; Indazole; Crystallography; Steric effects; Luminescence; Density functional theory; Photoluminescence; Single crystal; Platinum; Trifluoromethyl; Pyrazole; Intermolecular force; Photochemistry; Molecule; Stereochemistry; Computational chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001555346,0.0003224015,0.0002966732,0.0001617801,0.0001750155,0.0004705415,0.0006770077,0.0004008989,0.0009328707],"category_scores_gemma":[0.0002450849,0.0002793342,0.0001533235,0.0002380094,0.0002133783,0.0002278382,0.0002522663,0.0005458338,0.0004013907],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009255366,"about_ca_system_score_gemma":0.0002127765,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009846457,"about_ca_topic_score_gemma":0.001383903,"domain_scores_codex":[0.9998123,0.00002383093,0.00002102246,0.00005013032,0.00005226811,0.00004050678],"domain_scores_gemma":[0.9999127,0.000009608762,0.00001848102,0.00001987726,0.00001770796,0.00002151502],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009363846,0.00002464582,0.0001181615,0.0000428536,0.000004734628,0.00004795423,0.00003044641,0.0002145502,0.997308,0.0003225068,0.0001112248,0.001681153],"study_design_scores_gemma":[0.00002498718,0.0000653528,0.0003177322,0.000001724431,0.00000471029,0.00008125178,0.000006900778,0.0007644609,0.9975497,0.00002494042,0.001153073,0.00000511015],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9788154,0.0008896877,0.01430751,0.0002346838,0.00002715559,0.000134195,0.0004064429,0.0004539106,0.004730946],"genre_scores_gemma":[0.9874334,0.000380695,0.008876785,0.00006791534,0.000006568172,0.0000881402,0.0003434285,0.00004692645,0.002756149],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009846457,"threshold_uncertainty_score":0.006715298,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01174546464538073,"score_gpt":0.2122198949443123,"score_spread":0.2004744302989316,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}