{"id":"W2001605898","doi":"10.1139/v05-017","title":"Synthesis and characterization of cationic iron complexes supported by the neutral ligands NP<sup><i>i</i>-Pr</sup><sub>3</sub>, NArP<sup><i>i</i>-Pr</sup><sub>3</sub>, and NS<sup><i>t</i>-Bu</sup><sub>3</sub>","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Metalloenzymes and iron-sulfur proteins","field":"Energy","cited_by":53,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Cationic polymerization; Ligand (biochemistry); Phosphine; Thioether; Tris; Crystallography; Trigonal bipyramidal molecular geometry; Amine gas treating; Oxidation state; Molybdenum; Ferrous; Medicinal chemistry; Stereochemistry; Inorganic chemistry; Metal; Crystal structure; Polymer chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001239547,0.0001379153,0.0001253874,0.0001013314,0.0001400333,0.0001913685,0.0002226249,0.0002391023,0.0004623443],"category_scores_gemma":[0.0003178428,0.00007328978,0.00006814034,0.00006765512,0.0002158988,0.0001306018,0.0001291549,0.0001474724,0.0001182605],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002068597,"about_ca_system_score_gemma":0.0001378072,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006080536,"about_ca_topic_score_gemma":0.001005345,"domain_scores_codex":[0.9999143,0.00001098175,0.000006589635,0.00001808101,0.00003799469,0.00001206773],"domain_scores_gemma":[0.999864,0.00003085216,0.00004308361,0.00001190204,0.00003020417,0.00002011621],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003041757,0.00000643275,0.0001375418,0.00001496263,0.000001032426,0.00002387525,0.00002805768,0.0000809866,0.9986351,0.00003123092,0.000009315774,0.001001011],"study_design_scores_gemma":[0.000005108376,0.00009148391,0.0009852054,0.000001484896,0.000002986053,0.00008850619,0.0000147425,0.0005772245,0.997817,0.0000144752,0.0003996958,0.000002011883],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9963359,0.0001774114,0.002657065,0.00003094461,0.000002802082,0.00001298463,0.00005654191,0.00002359825,0.0007027182],"genre_scores_gemma":[0.9938846,0.0001492151,0.005097611,0.00001879297,0.000001968156,0.00001137166,0.0001032635,0.0000143901,0.0007186483],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006080536,"threshold_uncertainty_score":0.001546741,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007298543903582136,"score_gpt":0.1869982782378057,"score_spread":0.1796997343342236,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}