{"id":"W2001640490","doi":"10.1016/j.jasms.2008.12.006","title":"Gas-phase reactivity of ruthenium carbonyl cluster anions","year":2008,"lang":"en","type":"article","venue":"Journal of the American Society for Mass Spectrometry","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; British Columbia Knowledge Development Fund; University of Victoria","keywords":"Chemistry; Ruthenium; Mass spectrometry; Electrospray ionization; Reactivity (psychology); Phenylsilane; Dissociation (chemistry); Metal carbonyl; Carbon monoxide; Cluster chemistry; Photochemistry; Cluster (spacecraft); Chemical ionization; Metal; Ionization; Organic chemistry; Catalysis; Ion; Chromatography","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003721068,0.0002245385,0.0006429707,0.0001034792,0.0002386741,0.00001628144,0.0007485421,0.0000854336,0.0002772528],"category_scores_gemma":[0.0001226365,0.0001658497,0.001845428,0.001041294,0.0005402344,0.0001121216,0.0001015973,0.0005895169,8.098476e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003191439,"about_ca_system_score_gemma":0.0001567825,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004507827,"about_ca_topic_score_gemma":0.000001041402,"domain_scores_codex":[0.998242,0.00002714328,0.0006427416,0.000214899,0.000504408,0.0003688762],"domain_scores_gemma":[0.9967651,0.0003178421,0.001893672,0.0006610336,0.0002323032,0.0001300105],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000137232,0.0005480279,0.002382359,0.00005475162,0.0003289282,0.000001827578,0.0001655009,0.000006552763,0.9822119,0.0009749585,0.01268634,0.0005015687],"study_design_scores_gemma":[0.002914547,0.001027377,0.002694199,0.00009493191,0.0005223508,0.0006754028,0.001710292,0.0006575423,0.9524568,0.01133752,0.02534697,0.0005620608],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9799554,0.0001512334,0.01242591,0.002639922,0.00007772387,0.0001685079,0.000140787,0.00004756506,0.004392956],"genre_scores_gemma":[0.9382579,0.000389606,0.06019081,0.0002053493,0.0003991766,0.00001717105,0.000003500194,0.00004211863,0.0004943592],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0477649,"threshold_uncertainty_score":0.6763153,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01646829032178066,"score_gpt":0.2854900822247992,"score_spread":0.2690217919030186,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}