{"id":"W2001696690","doi":"10.1039/b618345j","title":"Rapid oxygen ion diffusion and surface exchange kinetics in PrBaCo2O5+x with a perovskite related structure and ordered A cations","year":2007,"lang":"en","type":"article","venue":"Journal of Materials Chemistry","topic":"Advancements in Solid Oxide Fuel Cells","field":"Materials Science","cited_by":584,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; U.S. Department of Energy","keywords":"Oxygen; Perovskite (structure); Kinetics; Oxide; Conductivity; Chemistry; Oxygen transport; Diffusion; Crystallite; Electrical resistivity and conductivity; Cathode; Inorganic chemistry; Materials science; Analytical Chemistry (journal); Physical chemistry; Crystallography; Thermodynamics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005967666,0.0001798429,0.0003233255,0.00004333702,0.00005555003,0.00007948362,0.0001389937,0.000139356,0.0006722563],"category_scores_gemma":[0.0001000995,0.0001402329,0.00001370342,0.0001166659,0.0001280612,0.0001989222,0.00009216679,0.0001362736,0.000001157854],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007786415,"about_ca_system_score_gemma":0.0000358428,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008691555,"about_ca_topic_score_gemma":0.000008856777,"domain_scores_codex":[0.9986188,0.00004668667,0.0006108219,0.0002048709,0.0002697353,0.0002490843],"domain_scores_gemma":[0.9989304,0.00007554156,0.0005810031,0.0001661495,0.0001300529,0.0001168397],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002618078,0.00005307147,0.0003900607,0.000212617,0.000008175158,0.00004799838,0.0006540481,0.00005226973,0.998169,0.000001827198,0.00003528455,0.0001138574],"study_design_scores_gemma":[0.001223921,0.00008969603,0.005373844,0.0002493873,0.0000266954,0.0004627562,0.0003022991,0.000005618229,0.9914576,0.0001228951,0.0005234009,0.0001619248],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9983446,0.0009459736,0.00008901129,0.0001168512,0.0002131818,0.0001398982,0.00003739675,0.00001092106,0.0001021617],"genre_scores_gemma":[0.9923631,0.0005018495,0.00677057,0.0000276206,0.0001136677,8.799061e-7,0.000007147089,0.00002238442,0.0001927562],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006711421,"threshold_uncertainty_score":0.7360735,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006948897865407099,"score_gpt":0.2309464021451582,"score_spread":0.2239975042797512,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}