{"id":"W2001704521","doi":"10.1021/ic001303x","title":"Contrasting Formation of a (Phenylthio)phosphinimine and (Phenylthio)phosphazide. Synthesis of Metal Complexes","year":2001,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Ligand (biochemistry); Metal; Medicinal chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002672602,0.0003409027,0.0008453921,0.00004859452,0.0001034956,0.00002857529,0.0003946721,0.0001918562,0.01429172],"category_scores_gemma":[0.0006822303,0.0003412928,0.0002222545,0.0003492919,0.0002615391,0.0001920657,0.0001974733,0.0001954037,0.000007113822],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006748945,"about_ca_system_score_gemma":0.00006901522,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008466243,"about_ca_topic_score_gemma":0.00000668925,"domain_scores_codex":[0.9977852,0.00001631159,0.001020766,0.000409925,0.0004119565,0.0003558352],"domain_scores_gemma":[0.9978521,0.0005242843,0.0007067354,0.0005921827,0.0001754376,0.0001492453],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003565611,0.0001791694,0.002392399,0.001016921,0.0001963087,0.000006109775,0.0002513527,0.000001833923,0.9826871,0.00005819235,0.00002887252,0.01314604],"study_design_scores_gemma":[0.0005148811,0.00001232551,0.001493892,0.0001988091,0.0003535438,0.0001239988,0.000950055,0.0003719352,0.994311,0.0001797867,0.001175259,0.0003145389],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.986554,0.001818984,0.0001872631,0.0001229143,0.00002261965,0.00006558334,0.0001084356,0.00007636102,0.01104385],"genre_scores_gemma":[0.9985597,0.0002779813,0.000364723,0.00001763612,0.0001001662,0.00001680342,0.0000428831,0.00004484236,0.0005752808],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01428461,"threshold_uncertainty_score":0.9999039,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01222562668325377,"score_gpt":0.2117610278911094,"score_spread":0.1995354012078557,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}