{"id":"W2001730542","doi":"10.1139/v06-094","title":"Synthesis and characterization of 2,7-bis(2-pyridyl)-1,8-diazaanthraquinone — A redox-active ligand designed for the construction of supramolecular grids","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Semiquinone; Supramolecular chemistry; Redox; Quinone; Electrochemistry; Ligand (biochemistry); Anthraquinone; Pyridine; Combinatorial chemistry; Non-innocent ligand; One-electron reduction; Photochemistry; Polymer chemistry; Crystal structure; Stereochemistry; Crystallography; Medicinal chemistry; Inorganic chemistry; Organic chemistry; Electrode","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003211166,0.00009497388,0.0002290337,0.00006595324,0.00009916228,0.00003946906,0.0001783364,0.00007050952,0.000235804],"category_scores_gemma":[0.0003091342,0.00008186599,0.00005972827,0.0001097116,0.000379565,0.0001294917,0.000009006497,0.00005779979,1.686414e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004834761,"about_ca_system_score_gemma":0.0005302533,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007046875,"about_ca_topic_score_gemma":0.0001540684,"domain_scores_codex":[0.9991453,0.00003291085,0.0004254343,0.0001041052,0.0001471014,0.0001451688],"domain_scores_gemma":[0.9985013,0.0002461902,0.0005972694,0.0001316498,0.0004186865,0.0001049233],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004759803,0.000008152305,0.0001996358,0.00009959815,0.0000135487,0.000003663844,0.00006467245,0.00001703517,0.9978621,0.0001088419,0.0001318182,0.001443331],"study_design_scores_gemma":[0.0002570223,0.00004330606,0.003298182,0.00008217237,0.00005296625,0.0001227768,0.0001404046,0.00005676874,0.9947978,0.000290065,0.0007825514,0.00007598528],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9941982,0.0002298557,0.00426471,0.0006187819,0.0001507286,0.0001236839,0.0002257337,0.000002832611,0.0001854416],"genre_scores_gemma":[0.9982973,0.0000206867,0.001469365,0.00001335149,0.0001345343,0.000007970428,0.000007209551,0.00001015887,0.00003936901],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004099122,"threshold_uncertainty_score":0.3338398,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007593571559512062,"score_gpt":0.2021485614575855,"score_spread":0.1945549898980735,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}