{"id":"W2001859185","doi":"10.1021/om030646a","title":"Compatibility of the Vinylidene Ligand and Perfluorophenoxide","year":2004,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Deprotonation; Dication; Ligand (biochemistry); Nucleophile; Medicinal chemistry; Moiety; Stereochemistry; Butane; Acetylide; Ion; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002426416,0.0001651522,0.0002706742,0.00001357117,0.00008164265,0.00001867522,0.0003432208,0.0001085563,0.0009424633],"category_scores_gemma":[0.0005365619,0.0001237806,0.00008213264,0.0002066003,0.0003141783,0.00004088261,0.0002355697,0.0001786133,0.000006776528],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009055116,"about_ca_system_score_gemma":0.0001005512,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004417448,"about_ca_topic_score_gemma":0.000008484097,"domain_scores_codex":[0.9989629,0.00002045186,0.0003121279,0.0002858067,0.000236947,0.0001817109],"domain_scores_gemma":[0.9988099,0.0001309815,0.0001457534,0.0007737406,0.00005566814,0.00008400057],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000006163057,0.00008258898,0.00598361,0.0001316111,0.00002966679,9.353035e-7,0.0003013215,0.000006464469,0.9917626,0.0002965089,0.000003770052,0.001394695],"study_design_scores_gemma":[0.0004415726,0.000006533648,0.006412653,0.00003987702,0.00005267803,0.0000351953,0.0001706938,0.000006539357,0.9896877,0.002384884,0.0006290377,0.0001326531],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9935157,0.0003111257,0.0001642673,0.000351416,0.00005848882,0.0000501617,0.00001745512,0.00003808412,0.005493289],"genre_scores_gemma":[0.9950058,0.0000343488,0.004316726,0.00003205811,0.00005985613,0.000002340644,0.000001991233,0.00002795093,0.0005189069],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004974382,"threshold_uncertainty_score":0.9999708,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01167206640568499,"score_gpt":0.2285836070924782,"score_spread":0.2169115406867932,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}