{"id":"W2001916925","doi":"10.1039/c5cc01522g","title":"Expanding the scope of strained-alkyne chemistry: a protection–deprotection strategy via the formation of a dicobalt–hexacarbonyl complex","year":2015,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Alkyne; Bioorthogonal chemistry; Scope (computer science); Chemistry; Reactivity (psychology); Combinatorial chemistry; Catalysis; Organic chemistry; Click chemistry; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004845527,0.0008524964,0.0003415322,0.000224346,0.0001781473,0.0003725814,0.000468747,0.0005300663,0.001775272],"category_scores_gemma":[0.0003161417,0.0002413784,0.0002359472,0.0001660017,0.0003616809,0.0006361427,0.0004554031,0.0009287565,0.0007287133],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003545425,"about_ca_system_score_gemma":0.0005057706,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004996975,"about_ca_topic_score_gemma":0.0006647203,"domain_scores_codex":[0.999786,0.00002393559,0.00002872685,0.00006683423,0.00005305378,0.00004151478],"domain_scores_gemma":[0.9997713,0.0000505048,0.00006240949,0.00005000799,0.00003355444,0.00003215226],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006050188,0.00004136609,0.00008108679,0.0001946661,0.00000953112,0.0002588255,0.00004868825,0.0003925466,0.988956,0.001463316,0.000194521,0.008298825],"study_design_scores_gemma":[0.00002746871,0.0002173142,0.0002648695,0.00000886167,0.00001195881,0.0004143637,0.000008359104,0.0005459345,0.9898971,0.0001381296,0.008451298,0.00001432047],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.797367,0.01167301,0.1640379,0.00114565,0.0004598211,0.0008940255,0.0008507526,0.000725684,0.02284624],"genre_scores_gemma":[0.9432375,0.006772026,0.04510785,0.0002773918,0.00006547673,0.0001573485,0.0005047533,0.00007419337,0.003803469],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001775272,"threshold_uncertainty_score":0.005938828,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1417868795239075,"score_gpt":0.3436881331485923,"score_spread":0.2019012536246848,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}