{"id":"W2001985553","doi":"10.1021/om0498450","title":"A Chiral Bis(oxazoline) Phosphine with a Rigid Backbone:  Ligand Synthesis and Characterization of Products Obtained in Highly Diastereoselective Reactions with a Rhodium(I) Complex and a Tetrahedral “RhRu<sub>3</sub>” Cluster","year":2004,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Oxazoline; Ligand (biochemistry); Denticity; Ruthenium; Intramolecular force; Chirality (physics); Stereochemistry; Molecule; Coordination sphere; Phosphine; Chiral ligand; Crystallography; Crystal structure; Enantioselective synthesis; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001380867,0.0003088415,0.0004866784,0.0003987985,0.0000955014,0.00006059034,0.0001038884,0.000116271,0.00002798387],"category_scores_gemma":[0.00013169,0.0002503583,0.00003590735,0.001848248,0.0001873557,0.0003034187,0.00005507451,0.0001907847,0.000002459709],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001197367,"about_ca_system_score_gemma":0.000159694,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006948936,"about_ca_topic_score_gemma":0.0001887875,"domain_scores_codex":[0.9984826,0.00002372777,0.0004136075,0.0005122541,0.00028603,0.0002817356],"domain_scores_gemma":[0.9990141,0.00007101715,0.0003058022,0.0002854326,0.0001961547,0.0001275237],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003721135,0.000413493,0.005557704,0.0002844787,0.0002684815,0.00001336264,0.001161727,0.00003122829,0.9886681,0.0001758664,0.000001535949,0.003051844],"study_design_scores_gemma":[0.002502526,0.0001416365,0.03690683,0.0001332251,0.000233197,0.0001093503,0.0002275046,0.000314188,0.9587848,0.00002895979,0.0002274584,0.0003903209],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978806,0.00005923832,0.0005441569,0.0005842617,0.000009519106,0.0002689252,0.00009720989,0.00005412494,0.0005019148],"genre_scores_gemma":[0.9984928,0.0001562057,0.0007490736,0.00006097084,0.00004836963,0.00005857656,0.00024236,0.00005412477,0.0001374956],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03134913,"threshold_uncertainty_score":0.9999949,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007668391598185627,"score_gpt":0.1910346565729781,"score_spread":0.1833662649747924,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}