{"id":"W2001985553","doi":"10.1021/om0498450","title":"A Chiral Bis(oxazoline) Phosphine with a Rigid Backbone:  Ligand Synthesis and Characterization of Products Obtained in Highly Diastereoselective Reactions with a Rhodium(I) Complex and a Tetrahedral “RhRu<sub>3</sub>” Cluster","year":2004,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Oxazoline; Ligand (biochemistry); Denticity; Ruthenium; Intramolecular force; Chirality (physics); Stereochemistry; Molecule; Coordination sphere; Phosphine; Chiral ligand; Crystallography; Crystal structure; Enantioselective synthesis; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001353508,0.0003174368,0.0001668978,0.0001025246,0.0001073126,0.0003128051,0.000288319,0.0002438198,0.001269309],"category_scores_gemma":[0.0001871878,0.0001339695,0.000114469,0.0001115441,0.0002186092,0.0001707191,0.0001903569,0.0003167049,0.0006178954],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003297891,"about_ca_system_score_gemma":0.0002552572,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005792042,"about_ca_topic_score_gemma":0.0009086706,"domain_scores_codex":[0.9999027,0.00002005179,0.000006075978,0.00001987151,0.00002593168,0.00002522884],"domain_scores_gemma":[0.9998974,0.00001497548,0.00002725835,0.00001393007,0.00001231998,0.00003411866],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001009371,0.00001596831,0.00006770366,0.00004079334,0.000004241725,0.00009881536,0.00002789928,0.0003217077,0.9976321,0.0002434222,0.0000563655,0.00138985],"study_design_scores_gemma":[0.00001420512,0.00009982847,0.0002290036,0.000001791519,0.000004219067,0.0001008768,0.000008722533,0.0005505513,0.9979671,0.00002180239,0.0009985538,0.000003420395],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.979287,0.0003610346,0.01284442,0.0001179537,0.00001874882,0.00005308026,0.0004470889,0.0003243965,0.006546101],"genre_scores_gemma":[0.9898266,0.0001909688,0.006035939,0.00004020081,0.000004874526,0.00002411516,0.0003838329,0.00008257131,0.003411005],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001269309,"threshold_uncertainty_score":0.004246294,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007668391598185627,"score_gpt":0.1910346565729781,"score_spread":0.1833662649747924,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}