{"id":"W2002054556","doi":"10.1039/b716114j","title":"Liganddirected self-assembly of polymetallic [n × n] grids: rational routes to large functional molecular subunits?","year":2007,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":105,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Rational design; Grid; Ligand (biochemistry); Redox; Yield (engineering); Chemistry; Metal; Self-assembly; Combinatorial chemistry; Metal ions in aqueous solution; Nanotechnology; Crystallography; Materials science; Receptor; Inorganic chemistry; Mathematics; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002967721,0.0002233108,0.0002719167,0.0001808259,0.0002584372,0.00003481138,0.0002126856,0.0002105002,0.00482798],"category_scores_gemma":[0.00004897555,0.0002332761,0.0002113842,0.0007279812,0.00003212287,0.0001239424,0.000009711717,0.0002893412,0.0001119587],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007742695,"about_ca_system_score_gemma":0.0001258072,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004947259,"about_ca_topic_score_gemma":0.00009587951,"domain_scores_codex":[0.9982653,0.00002276945,0.0005393837,0.0003736239,0.000425622,0.0003732472],"domain_scores_gemma":[0.9987021,0.0002835069,0.0001320602,0.0004455476,0.0002023539,0.0002344447],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004336194,0.0008297449,0.000165136,0.00004805306,0.0002513341,0.000002772408,0.0001953601,0.000179547,0.9857897,0.009656194,0.0002569717,0.002581791],"study_design_scores_gemma":[0.0003862332,0.0000199864,0.002605291,0.00003806256,0.0001655556,0.0000129444,0.0002235634,0.0002987763,0.9726192,0.0001588874,0.02320652,0.0002649302],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.4256288,0.0002130635,0.5673721,0.0005886283,0.0001430956,0.0001632365,0.0003008081,0.0002433181,0.005346956],"genre_scores_gemma":[0.993391,0.00003377954,0.004777242,0.0002045915,0.0001296282,0.00007948148,0.0001755952,0.00004381108,0.001164811],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.5677622,"threshold_uncertainty_score":0.9960818,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01041956082770842,"score_gpt":0.2337580937184961,"score_spread":0.2233385328907877,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}