{"id":"W2002161675","doi":"10.1021/ma034980u","title":"Polysulfone-<i>g</i><i>raft</i>-poly(<i>tert</i>-butyl acrylate):  Synthesis, Nanophase Separation, Poly(<i>tert</i>-butyl acrylate) Hydrolysis, and pH-Dependent Iridescence","year":2003,"lang":"he","type":"article","venue":"Macromolecules","topic":"Polymer Surface Interaction Studies","field":"Materials Science","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"Defence Research and Development Canada; University of Calgary","funders":"","keywords":"Polysulfone; Acrylate; Butyl acrylate; Polymer chemistry; Materials science; Copolymer; Acrylic acid; Hydrolysis; Iridescence; Chemical engineering; Chemistry; Polymer; Organic chemistry; Composite material; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001167152,0.000787176,0.0001564743,0.0001670408,0.0001402203,0.0001134554,0.0001616116,0.0001949969,0.001175582],"category_scores_gemma":[0.0001290544,0.0001565086,0.000174834,0.0002558278,0.0001585251,0.0002563735,0.0001126235,0.0004155809,0.0005986405],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003043831,"about_ca_system_score_gemma":0.0002369457,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008189249,"about_ca_topic_score_gemma":0.001207026,"domain_scores_codex":[0.9999112,0.00001004494,0.000006743149,0.00002702527,0.00002418391,0.00002077266],"domain_scores_gemma":[0.9998993,0.00001413065,0.00003883844,0.00001146435,0.00001518642,0.00002114279],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003351011,0.000007862555,0.00003071385,0.00002212565,0.000001966321,0.0000195589,0.000006892303,0.0000607816,0.999203,0.00003694322,0.00001642762,0.0005601838],"study_design_scores_gemma":[0.000002533051,0.0000311025,0.000242919,6.494415e-7,0.000001629546,0.0000245505,0.000001768111,0.0001634782,0.9991834,0.000006632774,0.0003399574,0.000001465591],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9861644,0.000567389,0.009585366,0.00005344213,0.00001818485,0.00008420457,0.0006754436,0.0002601082,0.002591404],"genre_scores_gemma":[0.9846833,0.000741253,0.008071857,0.00003679485,0.00000594423,0.000102419,0.0009889911,0.00009201762,0.005277364],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001175582,"threshold_uncertainty_score":0.003932714,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01275295934159613,"score_gpt":0.2720909923285987,"score_spread":0.2593380329870026,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}