{"id":"W2002161675","doi":"10.1021/ma034980u","title":"Polysulfone-<i>g</i><i>raft</i>-poly(<i>tert</i>-butyl acrylate):  Synthesis, Nanophase Separation, Poly(<i>tert</i>-butyl acrylate) Hydrolysis, and pH-Dependent Iridescence","year":2003,"lang":"he","type":"article","venue":"Macromolecules","topic":"Polymer Surface Interaction Studies","field":"Materials Science","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"Defence Research and Development Canada; University of Calgary","funders":"","keywords":"Polysulfone; Acrylate; Butyl acrylate; Polymer chemistry; Materials science; Copolymer; Acrylic acid; Hydrolysis; Iridescence; Chemical engineering; Chemistry; Polymer; Organic chemistry; Composite material; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","insufficient_payload"],"consensus_categories":["metaepi_narrow","insufficient_payload"],"category_scores_codex":[0.002339638,0.002729594,0.00279325,0.0008184862,0.002350802,0.002481416,0.001868065,0.0009431823,0.003060302],"category_scores_gemma":[0.001427319,0.00274803,0.000785356,0.00147109,0.001729346,0.00213988,0.001274244,0.001232008,0.003767477],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006066609,"about_ca_system_score_gemma":0.0006901777,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001925217,"about_ca_topic_score_gemma":0.0005712309,"domain_scores_codex":[0.9845346,0.002179921,0.003251649,0.003975173,0.0024409,0.003617722],"domain_scores_gemma":[0.9918911,0.001403455,0.001829156,0.002806638,0.0006568507,0.001412797],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006420249,0.001001166,0.002478189,0.0003247384,0.0007037281,0.0008461211,0.00271089,0.00004510437,0.9832673,0.0004983998,0.003454012,0.004028321],"study_design_scores_gemma":[0.002395733,0.0003965321,0.000749959,0.0007449202,0.0009930335,0.001206007,0.001507103,0.0003162059,0.9644178,0.0003926049,0.02401093,0.002869186],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8974795,0.08234575,0.00278928,0.003166081,0.005176599,0.001696078,0.001410421,0.000766509,0.005169804],"genre_scores_gemma":[0.9814361,0.006418513,0.002006674,0.002782325,0.0004183874,0.0003829432,0.00004851661,0.0003751138,0.006131466],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08395658,"threshold_uncertainty_score":0.998948,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01275295934159613,"score_gpt":0.2720909923285987,"score_spread":0.2593380329870026,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}