{"id":"W2002246787","doi":"10.1021/om0003178","title":"Titanium Complexes of Sterically Demanding Cage-Phosphinimide Ligands","year":2000,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Steric effects; Adduct; Catalysis; Trimethylsilyl; Ligand (biochemistry); Titanium; Ethylene; Medicinal chemistry; Polymerization; Activator (genetics); Stereochemistry; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001489678,0.0003959247,0.0003071454,0.0001450952,0.0001657409,0.0005056464,0.0007688683,0.0004998575,0.002146852],"category_scores_gemma":[0.0002951664,0.000209512,0.0001298114,0.0001642973,0.0002446999,0.0003154622,0.0004835198,0.0004872005,0.0005983043],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007957565,"about_ca_system_score_gemma":0.0002269068,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005549859,"about_ca_topic_score_gemma":0.001039271,"domain_scores_codex":[0.9998541,0.00002649404,0.000008618239,0.00002950482,0.00004110191,0.00004020036],"domain_scores_gemma":[0.9998653,0.00002517402,0.00004672858,0.0000109905,0.00001512138,0.00003662616],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000379684,0.000047585,0.0001632282,0.0002244617,0.00001899393,0.0001063719,0.00005847866,0.0007551044,0.9936653,0.001409711,0.0003010322,0.002870112],"study_design_scores_gemma":[0.000123122,0.0005983951,0.0005394525,0.00001114654,0.00003507123,0.0001768048,0.00002670726,0.002405325,0.9892225,0.0001197917,0.006723979,0.00001781624],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9849355,0.001199988,0.007360367,0.0001234876,0.00005242228,0.00007427021,0.0002314447,0.0002548814,0.005767719],"genre_scores_gemma":[0.989777,0.0005621276,0.004632967,0.00007116406,0.00001514678,0.00005837545,0.0002729605,0.00003916071,0.0045711],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002146852,"threshold_uncertainty_score":0.007181883,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0105942476718918,"score_gpt":0.2119566041098337,"score_spread":0.2013623564379419,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}