{"id":"W2002246787","doi":"10.1021/om0003178","title":"Titanium Complexes of Sterically Demanding Cage-Phosphinimide Ligands","year":2000,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Steric effects; Adduct; Catalysis; Trimethylsilyl; Ligand (biochemistry); Titanium; Ethylene; Medicinal chemistry; Polymerization; Activator (genetics); Stereochemistry; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001836766,0.0003311302,0.0007165346,0.0001124917,0.0001453554,0.00007402077,0.0006091612,0.0001398842,0.2623194],"category_scores_gemma":[0.0000562557,0.0003130723,0.0003232833,0.0006174525,0.000176718,0.0001653072,0.0001212207,0.000176898,0.0003713688],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007305026,"about_ca_system_score_gemma":0.00005214243,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004634138,"about_ca_topic_score_gemma":0.00001311589,"domain_scores_codex":[0.9979664,0.00001436226,0.0006922994,0.0004693075,0.0004272123,0.0004304069],"domain_scores_gemma":[0.9986205,0.0001233714,0.0002063424,0.0007891168,0.00007287408,0.0001878227],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006314173,0.0003338039,0.001689891,0.0001770781,0.0003627632,0.00001227817,0.0003224292,0.00001427186,0.9373655,0.001255124,0.0001714164,0.05823235],"study_design_scores_gemma":[0.0005248635,0.00006624504,0.00375722,0.00007149363,0.0003481786,0.00002889372,0.0002912752,0.0001880925,0.8414041,0.000589863,0.1520181,0.0007116254],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9188614,0.0004457549,0.0001266577,0.0001288237,0.00004459913,0.00005567562,0.00008588181,0.0001291626,0.08012202],"genre_scores_gemma":[0.9783808,0.0003596728,0.0009229153,0.00007379011,0.0001400266,0.000009935269,0.00006370569,0.00007544773,0.01997371],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.261948,"threshold_uncertainty_score":0.9999321,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0105942476718918,"score_gpt":0.2119566041098337,"score_spread":0.2013623564379419,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}