{"id":"W2002357683","doi":"10.1021/jp905654v","title":"Structure of [Pb(Gly-H)]<sup>+</sup> and the Monosolvated Water and Methanol Solvated Species by Infrared Multiple-Photon Dissociation Spectroscopy, Energy-Resolved Collision-Induced Dissociation, and Electronic Structure Calculations","year":2009,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University; Memorial University of Newfoundland","funders":"","keywords":"Infrared multiphoton dissociation; Chemistry; Deprotonation; Dissociation (chemistry); Spectroscopy; Infrared spectroscopy; Solvent; Photochemistry; Mass spectrometry; Collision-induced dissociation; Ion; Tandem mass spectrometry; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007876641,0.0003725722,0.00034401,0.0001613946,0.0003905871,0.0002968674,0.0006873545,0.0002964126,0.004607446],"category_scores_gemma":[0.0001923344,0.0002091105,0.0001280584,0.0003089828,0.0003242207,0.0003054671,0.000210115,0.0003466176,0.0004250003],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006446019,"about_ca_system_score_gemma":0.0003302494,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003213755,"about_ca_topic_score_gemma":0.002456313,"domain_scores_codex":[0.9999373,0.000006614373,0.000001737967,0.00001424904,0.00002828859,0.00001184404],"domain_scores_gemma":[0.999964,0.000007804331,0.00001050621,0.000003015767,0.000008782599,0.00000588519],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001512828,0.0001080355,0.002595567,0.001054387,0.0001365951,0.0009010388,0.0004622907,0.05798028,0.8929998,0.01972675,0.004676958,0.0178455],"study_design_scores_gemma":[0.0004893557,0.0008172732,0.008632313,0.00005119635,0.00009372111,0.0008793928,0.0005022947,0.2877168,0.6730623,0.006340689,0.02131096,0.0001037523],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9795625,0.001263794,0.009209916,0.0002453627,0.00003133313,0.00003754332,0.0008677726,0.0002953785,0.008486324],"genre_scores_gemma":[0.988921,0.0004445171,0.006474853,0.00005937031,0.000006276136,0.00003882699,0.001381661,0.00006922432,0.002604183],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004607446,"threshold_uncertainty_score":0.0154134,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003930630590041503,"score_gpt":0.2213518417535242,"score_spread":0.2174212111634827,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}