{"id":"W2002410502","doi":"10.1002/chin.200327214","title":"Synthesis and Reactivity of Cyclic Sulfamidites and Sulfamidates.","year":2003,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Reactivity (psychology); Combinatorial chemistry; Organic chemistry; Stereochemistry; Alternative medicine","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00013269,0.0001255076,0.0002134352,0.00003206448,0.00005467779,0.00002162228,0.00006044953,0.00009883079,0.0003459144],"category_scores_gemma":[0.0006441054,0.000112485,0.00004304278,0.00006299171,0.000144295,0.0001496297,0.00002907944,0.00007936115,0.00000490667],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000023006,"about_ca_system_score_gemma":0.00002459725,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004106876,"about_ca_topic_score_gemma":0.000002999011,"domain_scores_codex":[0.9993812,4.066088e-7,0.0001944765,0.000164364,0.0001054907,0.0001540203],"domain_scores_gemma":[0.9991134,0.000408036,0.0001078803,0.0002641062,0.00002770343,0.00007884232],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001529095,0.0000909658,0.006488177,0.0003315538,0.00007271516,0.000002051605,0.0002655861,4.042822e-8,0.6402454,0.001417562,0.0006995462,0.3503712],"study_design_scores_gemma":[0.0001120851,0.000003097101,0.002823237,0.000041333,0.00004138534,0.00003722323,0.0004853311,0.000003356643,0.9738075,0.0001823237,0.02234037,0.000122801],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5888672,0.0002248665,2.930609e-7,0.00001924175,0.00001102951,0.00001826905,0.00001291692,0.00001814388,0.410828],"genre_scores_gemma":[0.9972546,0.000405775,0.00003783019,0.000008882274,0.00001892219,0.00001715114,0.000005408181,0.00001162213,0.002239882],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4085881,"threshold_uncertainty_score":0.4587007,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01270149866029934,"score_gpt":0.2178548202691491,"score_spread":0.2051533216088497,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}