{"id":"W2002711546","doi":"10.1002/jms.1779","title":"A fragmentation study of the Rhodamine 610 cation using visible‐laser desorption ionization","year":2010,"lang":"en","type":"article","venue":"Journal of Mass Spectrometry","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Fragmentation (computing); Desorption; Ion; Ionization; Rhodamine 6G; Rhodamine; Photochemistry; Analytical Chemistry (journal); Dye laser; Laser; Chromatography; Molecule; Fluorescence; Physical chemistry; Optics; Adsorption; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004401621,0.0001519123,0.0002488572,0.0003766884,0.0001430221,0.00005016055,0.0003703497,0.0001064868,0.001725087],"category_scores_gemma":[0.0001479056,0.0001173707,0.0001348221,0.001222286,0.00004219856,0.0002381992,0.00004592915,0.0005609886,0.000001689677],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000186729,"about_ca_system_score_gemma":0.00007533632,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003985912,"about_ca_topic_score_gemma":0.00002538183,"domain_scores_codex":[0.9983121,0.0000427347,0.0007246525,0.0001674079,0.0005894295,0.0001636782],"domain_scores_gemma":[0.9978301,0.0000714234,0.001252753,0.0004287945,0.0003533311,0.00006360521],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002786886,0.0006293281,0.03097196,0.00003201755,0.00005037474,0.000001573358,0.0001265412,0.0001995052,0.9666175,0.0008682061,0.00004728579,0.0004278537],"study_design_scores_gemma":[0.001177948,0.0002876023,0.0289086,0.00006051001,0.0002177239,0.0001282051,0.001159038,0.001767665,0.9616716,0.004287548,0.0001435211,0.0001900191],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9866567,0.00002374815,0.01158364,0.0001546967,0.0001789228,0.0001818344,0.000005916251,0.00002556105,0.001189024],"genre_scores_gemma":[0.9826408,0.00002239732,0.01684584,0.00001481975,0.0003221808,0.000007232556,0.000005385936,0.0000247465,0.0001166068],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005262195,"threshold_uncertainty_score":0.9991875,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01313405254102321,"score_gpt":0.280553969438838,"score_spread":0.2674199168978147,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}