{"id":"W2003055909","doi":"10.1002/pola.1187","title":"Modified polysulfones. IV. Synthesis and characterization of polymers with silicon substituents for a comparative study of gas‐transport properties","year":2001,"lang":"en","type":"article","venue":"Journal of Polymer Science Part A Polymer Chemistry","topic":"Synthesis and properties of polymers","field":"Materials Science","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"","keywords":"Electrophile; Silylation; Polysulfone; Chemistry; Trimethylsilyl; Metalation; Polymer chemistry; Polymer; Electrophilic substitution; Heteroatom; Reactivity (psychology); Silyl ether; Ether; Organosilicon; Organic chemistry; Ring (chemistry); Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0008298937,0.0003571455,0.0009355064,0.0002390462,0.000257337,0.0000675566,0.0007461983,0.00009083177,0.0001850186],"category_scores_gemma":[0.00006016112,0.0002510326,0.0001370962,0.0005543355,0.001473026,0.0008569847,0.00006643085,0.0001268185,8.73131e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005436729,"about_ca_system_score_gemma":0.0004912141,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000351666,"about_ca_topic_score_gemma":0.00001364364,"domain_scores_codex":[0.9967045,0.00006833297,0.001177713,0.0004701193,0.001055834,0.0005234901],"domain_scores_gemma":[0.9973468,0.00009762874,0.001435395,0.0004094766,0.0004231074,0.0002876421],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001646101,0.0006579661,0.007270347,0.000118366,0.000092034,0.000007120997,0.004272774,0.000007816507,0.9847615,0.000006052756,0.00000259181,0.001157371],"study_design_scores_gemma":[0.001194563,0.000544163,0.001937584,0.0003368071,0.0002409213,0.0001157825,0.004893078,0.0001057021,0.9903273,0.000001274718,0.00000910587,0.0002937333],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9962653,0.002720151,0.00005463362,0.0001650196,0.0002004592,0.0003363717,0.00004671891,0.00001424436,0.0001971098],"genre_scores_gemma":[0.9994448,0.00007144684,0.00002793732,0.00002670599,0.0001066694,0.00004181248,0.000001545708,0.00002498959,0.0002541351],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005565826,"threshold_uncertainty_score":0.9999942,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03594381321280857,"score_gpt":0.2493877031515175,"score_spread":0.2134438899387089,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}